A kind of lithium-ion battery non-aqueous electrolytic solution and lithium-ion battery comprising the electrolytic solution
A non-aqueous electrolyte and lithium-ion battery technology, applied in the field of lithium-ion batteries, can solve the problems that affect the actual use of batteries, the viscosity of the electrolyte is high, and the battery cycle performance and low-temperature performance cannot be considered.
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Embodiment 1
[0048] 1) Preparation of non-aqueous electrolyte:
[0049] In a 99.999% nitrogen glove box, mix ethylene carbonate (EC), ethylmethyl carbonate (EMC) and diethyl carbonate (DEC) in a mass ratio of 1:1:1, and then add lithium hexafluorophosphate to a concentration of 1.0mol / L; In the above mixed solution containing lithium salt, add the components shown in the mass percentage of Example 1 in Table 1, and mix evenly.
[0050] 2) Production of lithium-ion batteries:
[0051] The electrolyte was injected into the ternary material Li(Ni 0.5 co 0.2 mn 0.3 )O 2 In a soft-packed lithium-ion battery with the positive electrode and the graphite material as the negative electrode, charge with a constant current of 0.05C for 1 hour, then charge with a constant current of 0.2C to 4.0V, and then charge to 4.2V with a current of 0.05C, and finally put the battery in 55 Aged in an oven at ℃ for 24h, and discharged to 3.0V with a constant current of 0.2C.
[0052] 3) Li-ion battery perfor...
Embodiment 2~14
[0063] This embodiment is used to illustrate the lithium-ion battery non-aqueous electrolyte disclosed by the present invention and its preparation method, including most of the operating steps in Example 1, the difference being:
[0064] In the preparation step of the non-aqueous electrolytic solution, the non-aqueous electrolytic solution is added with the components shown in Table 1, Example 2-Example 14 in mass percentage.
[0065] The specific test method is consistent with that of Example 1, and the test results are shown in Table 2.
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