Slurry mixing process of lithium ion battery slurry

A lithium-ion battery and slurry technology, applied in secondary batteries, battery electrodes, circuits, etc., can solve the problems affecting the uniformity and fluidity of the slurry, the performance of the lithium-ion battery, and the utilization rate of raw materials, etc. Contact and dispersion effects, enhanced kneading and shearing effects, and improved pulp mixing efficiency

Inactive Publication Date: 2019-12-20
FENGFAN
View PDF9 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This wet slurry mixing process has a wide range of applications and lower performance requirements for equipment. However, in the preparation process, various conductive agents and active materials need to be dispersed step by step, and the conductive agent is difficult to disperse and easily agglomerates. , especially when the local concentration of the conductive agent is too high during feeding, severe agglomeration will occur, and the bonding effect of the binder will increase the particle size of the slurry, which will affect the uniformity and fluidity of the slurry, and ultimately affect the lithium impact on the performance of ion batteries
Although the slurry can be filtered after the slurry is mixed, this can only remove the agglomerated raw materials with larger particle sizes, and the larger agglomerated particles that can pass through the filter layer will still affect the fluidity of the slurry and be filtered out. The filter residue becomes waste, which not only seriously affects the utilization rate of raw materials, but also increases the cost
The whole pulping process usually takes 13-15 hours, the pulping time is long, the kinetic energy consumed in the production process is high, and the production efficiency is low

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1: A kind of slurry mixing process of positive electrode slurry of lithium ion battery, calculated by weight ratio, active material is nickel cobalt lithium manganese oxide Li(NiCoMn)O of 53 parts 2 2 parts of Ketjen Black ECP and 3 parts of conductive carbon black super-P as the conductive agent, 2 parts of modified polyvinylidene fluoride PVDF as the binder, and 40 parts of N-methylpyrrolidone NMP as the solvent, It includes the following steps:

[0027] 1. Glue making: Stir the amount of PVDF and 50-70% (can be 20 parts, 24 parts, 26 parts, 28 parts, etc.) of NMP solvent in a double planetary mixer to make glue. The revolution speed of the planetary mixer is any value between 25-60 rpm, preferably any value between 30-50 rpm, and the dispersion speed is any value between 1000-4500 rpm, preferably 1500 Any value in ~3000 rev / min, any value in the stirring time of 180-240 minutes.

[0028] 2. Dry mixing: the amount of nickel-cobalt lithium manganese oxide ...

Embodiment 2

[0044] Embodiment 2: A slurry mixing process of graphite mixed with amorphous carbon negative electrode slurry in a power lithium ion battery, the formula is as follows: calculated by weight ratio, including 34.5 parts of active material artificial graphite, 15.5 parts of active material hard carbon, 1 part of binder CMC, 2 parts of conductive agent Super-P and 1 part of binder SBR and 46 parts of deionized water solvent. It includes the following steps:

[0045] 1. Gluing: Mix the amount of CMC and 50-70% of the total amount (it can be 23 parts, 27.6 parts, 32.2 parts, 29.9 parts, etc.) of deionized water solvent in a double planetary mixer to make glue. Control the revolution speed of the double planetary mixer at any value from 25 to 60 rpm, preferably any value from 30 to 50 rpm, and the dispersion speed to any value from 1000 to 4500 rpm, preferably Any value in 1500~3000 rev / min, stirring time in any value in 180-240 minutes.

[0046] 2. Dry mixing: pre-mix the stated ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a slurry mixing process of lithium ion battery slurry. The slurry mixing process comprises the steps of: glue ejection: adding a binder and a solvent accounting for 50-70% of the total dosage into a double planetary agitator for high-speed stirring; dry mixing: pre-mixing an active material and a conductive agent in a powerful mixer for 4-20 minutes; mud-like stirring: adding a powder premix into glue prepared in the double planetary agitator for mud-like stirring; high-viscosity stirring: adding a solvent accounting for 15-25% of the total dosage into the double planetary agitator for high-viscosity stirring; high-speed stirring: adding a solvent accounting for 15-25% of the total dosage into the double planetary agitator for high-speed vacuum stirring; and defoaming: controlling a revolution speed of the double planetary agitator at 15 rpm / min and and controlling a dispersion speed at 0, performing low-speed vacuum defoaming, and stirring for 15-30 min to obtain the slurry. By adopting the slurry mixing process disclosed by the invention, the slurry can be dispersed more uniformly, the slurry has good sedimentation stability and rheological characteristics, and the slurry mixing process disclosed by the invention has the advantages of short time, low cost, low energy consumption and high efficiency.

Description

technical field [0001] The invention belongs to the technical field of lithium ion battery manufacturing, and relates to a slurry mixing process of lithium ion battery slurry. Background technique [0002] With the gradual intensification of competition in the new energy electric vehicle industry, the current market competition for power lithium-ion batteries is also becoming increasingly fierce. Lithium-ion batteries, as one of the mainstream technical route products, have gradually entered the performance-cost-equal stage from the stage of purely comparing performance. stage. [0003] The pulping process is the most important link to ensure the quality of batteries in the entire production process of lithium-ion batteries. In the electrode manufacturing of lithium-ion batteries, the positive and negative electrode slurries are basically composed of active materials, polymer binders, solvents and conductive agents. Regardless of the positive electrode slurry or the negati...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/04H01M4/139H01M10/0525B01F15/00
CPCH01M4/04H01M4/139H01M10/0525B01F35/22161B01F35/221422Y02E60/10
Inventor 顾志华高良秋高璐石琛俞晓峰刘慧洁
Owner FENGFAN
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products