A kind of long-acting antibacterial latex mattress and preparation method thereof
A technology of latex and mattresses, applied in the field of latex mattresses, can solve problems such as short duration of antibacterial effect, generation of cytotoxicity, and impact on user health, etc., and achieve enhanced antibacterial effect, excellent antibacterial effect, and excellent antibacterial effect
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[0029] The invention provides a kind of preparation method of long-acting antibacterial latex mattress, and its preparation process is as follows figure 1 described, including the following steps:
[0030] S1. Preparation of antibacterial agent: preparation of nanometer mesoporous TiO 2 , and the nanomesoporous TiO 2 Mix with silver nitrate solution according to the preset molar ratio to prepare silver-loaded nano-mesoporous TiO 2 ; For the silver-loaded nanometer mesoporous TiO 2 Carry out silanization treatment, and the silver-loaded nanometer mesoporous TiO after treatment 2 Mix with polyethyleneimine, disperse in methanol, and perform tertiary amination reaction; after the reaction, mix the product with hexadecane bromide and disperse in methanol for quaternization reaction; after the reaction, wash the product Dry to obtain quaternized silver-loaded nano-mesoporous TiO 2 , and then disperse it in deionized water to obtain an antibacterial agent;
[0031] S2. Prepara...
Embodiment 1
[0044] see figure 1 , the present embodiment provides a kind of preparation method of long-acting antibacterial latex mattress, comprises the steps:
[0045] S1, preparation of antibacterial agent
[0046] Preparation of Nano Mesoporous TiO 2 , and the nanomesoporous TiO 2 Mix with silver nitrate solution at a molar ratio of 1:3 to prepare silver-loaded nano-mesoporous TiO 2 ; The silver-loaded nanometer mesoporous TiO 2 Mix with ethanol and γ-aminopropyltriethoxysilane at a mass volume ratio of 1g:40mL:0.5mL, stir and react at 50°C for 12h, centrifuge the product, wash with absolute ethanol, and store at 50°C After drying under vacuum, the silanized silver-loaded nano-mesoporous TiO 2 ; Then the silver-loaded nanometer mesoporous TiO of described silanization 2 Mix with polyethyleneimine at a mass ratio of 2:1, disperse in methanol, and react at 3°C for 7 hours for tertiary amination reaction; after the reaction, mix the product with hexadecane bromide at a mass ratio...
Embodiment 2~5
[0059] Embodiment 2~5 provides a kind of preparation method of long-acting antibacterial latex mattress, compared with embodiment 1, the difference is that the reaction conditions of tertiary amination reaction and quaternization reaction in the step S1 are changed, each implementation The corresponding reaction conditions are shown in Table 2.
[0060] The reaction conditions of tertiary amination reaction and quaternization reaction in step S1 among the embodiment 2~5 of table 2
[0061]
[0062] The antibacterial properties of the long-acting antibacterial latex mattresses prepared in Examples 2 to 5 were tested under different time periods, and the results are shown in Table 3.
[0063] The antibacterial rate of the long-acting antibacterial latex mattress that table 3 embodiment 2~5 makes in different time periods
[0064]
[0065] As can be seen from Table 3, changing the relevant conditions of tertiary amination reaction and quaternization reaction has certain in...
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