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Preparation method of composite conductive fabric

By adding functionalized carbon nanotubes and dendritic conductive particles to polyacrylonitrile fibers, the problems of easy shedding and insufficient strength of conductive fibers were solved, and a composite conductive fabric with high conductivity and high tensile strength was achieved, ensuring Long lasting conductive properties.

Active Publication Date: 2020-11-20
DONGGUAN HEGUANG HEALTH MEDICAL TECHNOLOGY CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although there are many methods for preparing conductive fibers nowadays, there are some disadvantages in these preparation methods. For the conductive fibers prepared by the three methods 3, 4, and 5, the conductive layer on the surface of the fiber is easy to fall off during use, so that the fabric cannot be used. Long-term conductivity, 2. Fabrics woven from conductive fibers prepared by methods 1 and 2. Although they have long-term conductivity, the strength of the fabric will be greatly affected.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A composite conductive fabric mainly includes the following raw material components in parts by weight: 40 parts of polyacrylonitrile, 6 parts of functionalized carbon nanotubes and 12 parts of conductive particles.

[0033] A kind of manufacture method of composite conductive fabric, the manufacture method of described composite conductive fabric mainly comprises following preparation steps:

[0034] (1) Mix sulfuric acid with a mass fraction of 95% and nitric acid with a mass fraction of 70% at a volume ratio of 3:1 to obtain a mixed acid solution, mix the mixed acid solution with carbon nanotubes at a mass ratio of 10:1, and heat at temperature After stirring and reacting for 3 hours under the conditions of 45° C. and a rotating speed of 300 r / min, filter to obtain a functionalized carbon nanotube blank, wash the functionalized carbon nanotube blank 8 times with deionized water, and place it in a room at a temperature of 85° C. Dry for 3 hours under the condition;

[...

Embodiment 2

[0042] A composite conductive fabric mainly includes the following raw material components in parts by weight: 40 parts of polyacrylonitrile and 12 parts of conductive particles.

[0043] A kind of manufacture method of composite conductive fabric, the manufacture method of described composite conductive fabric mainly comprises following preparation steps:

[0044] (1) Mix porous silica and mixed acid solution at a mass ratio of 1:8, stir and react for 1 hour at a temperature of 45°C and a rotation speed of 300r / min, and then filter to obtain pretreated porous silica. Mix the pretreated porous silica and the mixed lye at a mass ratio of 1:8, stir and react for 1 hour at a temperature of 45°C and a rotation speed of 300r / min, and then filter to obtain a modified silica blank. After the silica blank was washed 5 times with deionized water, and dried for 2 hours at a temperature of 70°C, the modified silica was obtained, and the modified silica was mixed with 10% polyallylamine s...

Embodiment 3

[0051] A composite conductive fabric mainly includes the following raw material components in parts by weight: 40 parts of polyacrylonitrile, 6 parts of functionalized carbon nanotubes and 12 parts of conductive particles.

[0052] A kind of manufacture method of composite conductive fabric, the manufacture method of described composite conductive fabric mainly comprises following preparation steps:

[0053] (1) Mix sulfuric acid with a mass fraction of 95% and nitric acid with a mass fraction of 70% at a volume ratio of 3:1 to obtain a mixed acid solution, mix the mixed acid solution with carbon nanotubes at a mass ratio of 10:1, and heat at temperature After stirring and reacting for 3 hours under the conditions of 45° C. and a rotating speed of 300 r / min, filter to obtain a functionalized carbon nanotube blank, wash the functionalized carbon nanotube blank 8 times with deionized water, and place it in a room at a temperature of 85° C. Dry for 3 hours under the condition;

...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Abstract

The invention discloses a preparation method of a composite conductive fabric, and relates to the technical field of textile materials. The preparation method comprises the following steps of reactingdendritic porous silicon dioxide with poly(allylamine hydrochloride) and potassium chloropalladite; carrying out reduction, carbonization and alkaline etching to obtain a conductive particle blank; mixing the conductive particle blank with dopamine, and filtering the mixture to obtain conductive particles; and finally, mixing the conductive particles with functionalized carbon nanotubes, adding polyacrylonitrile and N,N-dimethylformamide to obtain a spinning solution, spinning the spinning solution into silks, and preparing a fabric from the silks to obtain the composite conductive fabric. The composite conductive fabric prepared by the method has excellent electrical conductivity and relatively high tensile strength.

Description

technical field [0001] The invention relates to the technical field of textile materials, in particular to a method for manufacturing a composite conductive fabric. Background technique [0002] In the current ever-changing Internet of Things technology, the research and development progress of intelligent clothing is extremely important, but the progress of the entire research and development is very slow due to the conductive problem of the fabric. [0003] The conductivity of the fabric depends on the conductivity of the fiber; nowadays, the preparation methods of conductive fibers mainly include the following: 1. Metal processing method, that is, using the conductivity of metal, metal conductive fibers can be obtained through certain processing methods ; 2. Spinning processing method, that is, direct spinning of conductive polymers (such as polyacetylene, polyaniline, polypyrrole, polythiophene, etc.) or conductive polymers, conductive particles (mainly carbon black or m...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/54D01F1/09D06M15/643D03D15/00D06M101/28
CPCD01F6/54D01F1/09D06M15/6436D03D15/00D06M2101/28D10B2321/10D10B2401/16
Owner DONGGUAN HEGUANG HEALTH MEDICAL TECHNOLOGY CO LTD