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A kind of superwetting surface and its preparation method and application

A super-wetting and scheme-based technology, which is applied in the field of super-wetting surfaces and its preparation, can solve problems such as limiting the application of materials, and achieve the effects of simple preparation process equipment, improved lipophilicity, and lasting and stable lipophilicity

Active Publication Date: 2022-03-29
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the super-wetting polymer surface prepared by the above method must be compounded with inorganic particles, and the brittleness of solid particles in flexible products limits the application of the material.
Therefore, until now, it is still not possible to prepare superamphiphilic polymer surfaces without the use of inorganic particles.

Method used

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  • A kind of superwetting surface and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0091] According to 100 mass parts of polypropylene surface (surface 1), maleic anhydride (5 mass parts) is dissolved in acetone (50 mass parts) to obtain maleic anhydride acetone solution; Sodium hydroxide (5 mass parts) is dissolved in de Aqueous sodium hydroxide solution was obtained in ionized water (50 parts by mass); the maleic anhydride acetone solution was added to the surface of the polypropylene under vacuum and fully contacted and mixed, and then the mixture was dried (80 ° C blast drying oven drying ). The mixture of dried maleic anhydride and polypropylene surface was microwaved (power 700W) for 5min under a nitrogen atmosphere; the microwaved product was soaked in deionized water for 10 minutes and replaced with deionized water for 3 times to ensure removal of untreated Participate in the maleic anhydride monomer of the grafting reaction, and then place it in an 80 ° C blast drying oven to dry the surface of the maleic anhydride grafted polypropylene; the sodium ...

Embodiment 2

[0094] According to 100 mass parts of polypropylene surface (with embodiment 1), maleic anhydride (5 mass parts) is dissolved in acetone (50 mass parts) to obtain maleic anhydride acetone solution; Sodium hydroxide (5 mass parts) is dissolved In deionized water (50 parts by mass), sodium hydroxide aqueous solution was obtained; the maleic anhydride acetone solution was added to the surface of the polypropylene under vacuum and fully contacted and mixed, and then the mixture was dried (80° C. oven dry). The mixture of dried maleic anhydride and polypropylene surface was microwaved (power 700W) for 5min under a nitrogen atmosphere; the microwaved product was soaked in deionized water for 10 minutes and replaced with deionized water for 3 times to ensure the removal of untreated The maleic anhydride monomer that participates in the grafting reaction is then placed in an 80°C blast oven to dry to obtain a dry maleic anhydride grafted polypropylene surface; an aqueous solution of s...

Embodiment 3

[0096] According to 100 mass parts of the polypropylene surface (same as Example 1), vinyl silicone oil (9 mass parts) is dissolved in ethanol (50 mass parts) to obtain vinyl silicone oil ethanol solution; sodium chloride (4 mass parts ) was dissolved in deionized water (50 parts by mass) to obtain an aqueous solution of sodium chloride; the vinyl silicone oil ethanol solution was added to the surface of the polypropylene under vacuum conditions to fully contact and mix, and then the mixture was dried (80 ° C blasting drying oven); the mixture of the dried vinyl silicone oil and the polypropylene surface is fully contacted and mixed with the sodium chloride aqueous solution, and then the mixture is dried (80°C blast drying oven); the dried mixture Microwave in a nitrogen atmosphere (power 1000W) for 3 minutes; soak the microwaved material in deionized water for 10 minutes and replace the deionized water for 3 times to ensure the removal of vinyl silicone oil monomers and sodium...

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Abstract

The invention provides a superwetting surface, its preparation method and application. The super-wetting surface is a grafted polypropylene surface with a micro-nano structure, grafted with hydrophilic side groups; or grafted with lipophilic side groups and hydrophilic side groups at the same time. The super-wetting surface is obtained by combining the components including the monomers of the hydrophilic side groups, or the monomers including the hydrophilic side groups and the monomers of the lipophilic side groups in The components inside are obtained by grafting the surface of polypropylene with microwave irradiation without adding a grafting initiator; it can also include further salinization of the surface of the grafted polypropylene obtained by reacting with hydroxide A step of. The polypropylene molecular weight on the super-wetting surface of the present invention does not decrease, has no residual monomers, no initiator residues, is colorless and odorless, and both the pure water flux and the oil flux are improved. The invention has simple preparation process, easy operation, simple preparation method and equipment, low cost and easy industrialization.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to a superwetting surface and its preparation method and application. Background technique [0002] The wettability of solid material surfaces is usually determined by the chemical properties and microstructure of the solid surface. Polymer surfaces with superwetting properties have important applications in liquid separation, self-cleaning, anti-fog, liquid transport, functional polymer films, printing, and bonding. [0003] At present, many scholars have conducted in-depth research on the surface modification of polymers, but most of the studies on superwetting materials are superhydrophobic materials, and there are very few reports on superhydrophilic materials. Obviously, superhydrophilic polymers are more difficult. preparation. The polymer surface obtained by traditional grafting methods, such as ATRP, corona method, plasma treatment, ultraviolet light, etc., can only be a h...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/18C08L23/12
CPCC08J7/18C08J2323/12
Inventor 乔金樑王崧合张晓红戚桂村宋志海蔡传伦王湘赖金梅李秉海蒋海斌茹越张江茹张红彬韩朋姜超郭照琰
Owner CHINA PETROLEUM & CHEM CORP