Polyurethane binder

A polyurethane adhesive, polyurethane prepolymer technology, applied in the direction of polyurea/polyurethane adhesives, adhesives, adhesive types, etc., can solve the problems of rising, infeasible, difficult to control, etc.

Inactive Publication Date: 2005-12-28
DINGSHENG SPECIAL CHEM
View PDF1 Cites 23 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But in fact, when the hydrogen oxygen value reaches 15, the viscosity increase value of the product has exceeded 20% per hour at 120 ° C, which is difficult to control in the actual production process, because it generally takes one to four hours or more from the completion of the reaction to the discharge. For a longer period of time, even if the screw ...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment I

[0036] Example I: As shown in Table 1, the composition of the hydroxyl-containing tackifier formed by unsaturated ester monomers in Example I-1 is 39wt% methyl methacrylate (MMA), 57.0wt% formazan Butyl acrylate (butyl 2-methyl-2-propenoate referred to as BMA), 4.0wt% dihydroxyethyl methacrylate (2-hydroxyethyl-2-methyl-2-propenoate referred to as HEMA); The value is 17.26 and its functionality is 3.5. The composition of the hydroxyl-containing tackifier formed by unsaturated ester monomers in Example I-2 is 40wt% methyl methacrylate (methyl 2-methyl-2-propenoate referred to as MMA), 54.5wt% Butyl methacrylate (butyl 2-methyl-2-propenoate referred to as BMA), 5.5% dihydroxyethyl methacrylate (2-hydroxyethyl 2-methyl-2-propenoate referred to as HEMA); the hydroxide value of the tackifier It is 22.00, and its functionality is 5.08. The composition of the hydroxyl-containing tackifier formed by unsaturated ester monomers in Example I-3 is wt40% methyl methacrylate (methyl 2-met...

Embodiment II

[0044]Example II: Another series of active macromolecular tackifiers are epoxy group-containing molecular structures similar to those in Example I, but the active groups are epoxy groups. In practical application, the epoxy group may coexist with other active groups. Only tackifiers containing epoxy groups were used as examples in this test. The experimental results are shown in Table 2. Characteristic product composition is shown in Example II. The composition of the epoxy-containing polymer tackifier formed by unsaturated ester monomers in Examples II-1 to II-2 is 50 wt% methyl methacrylate (methyl 2-methyl-2-propenoate is called for short MMA ), 47.00wt% butyl methacrylate (butyl-2-propenoate is called for short BMA) / 5.00wt% glycidyl methacrylate (oxiranylmethyl-2-propenoate is called for short GMA); the tackifier epoxy equivalent is 2840. The composition of the epoxy-containing polymer tackifier formed by unsaturated ester monomers in Examples II-3 to II-4 is 50 wt% met...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

Polyurethane adhesive consists of polyurethane performed polymer 70-90wt% and anchoring agent 10-30wt% which contains hydroxyl group or epoxy group and is prepared by polymerizing at least two unsaturated monomers from free radical. At lest one monomer is polymerized unsaturated monomer containing hydroxyl group or epoxy group with hydroxyl group value:15.5-55, functionality:2-6; epoxy equivalent:1420-7000 and functionality:2-6. It achieves good viscidity and thermal stability, and better heat resistance. It can be used for composite plate, foam polypropylene and polyester plastic.

Description

technical field [0001] The invention relates to a polyurethane adhesive. Background technique [0002] U.S. Patent US586656 The patent invented by Huang uses reactive polyacrylate or other polymers synthesized from unsaturated monomers as raw materials to produce reactive moisture-curing hot-melt products. The isocyanate group of this hot-melt product The content is 1-3%. In order to stabilize the final product, the invention points out that the hydroxyl value of the polymerized product of unsaturated monomers is between 5-15, not more than 15%. Otherwise, cross-linking will occur during the production process and lose its use value. If the hydrogen oxygen value is too low, the heat resistance effect will not be achieved. At the same time, the patent pointed out that the amount of this hydroxyl group-containing high polymer must be between 30-90% to achieve its performance. The patent pointed out that the ideal polymer molecule should be around 12000. But in fact, when ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C09J175/04
Inventor 袁淑芬
Owner DINGSHENG SPECIAL CHEM
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products