Dust repellant compositions

a technology of compositions and dust, applied in the field of dust repellant compositions, can solve the problems of poor compatibility of dust and dust, disadvantage of low ph, and detrimental to the environment and human safety, and achieve the effect of maintaining the appearance of the wheel and the tir

Inactive Publication Date: 2006-02-16
PETROFERM INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0005] A method has now been discovered in which a composition may be applied to surfaces in general and vehicle wheels, wheel covers and tires in particular, that delivers a film that is repellant to soils, dust (including brake dust) and grime. Furthermore, the delivery method is in a manner that typical consumers can use safely to apply the film to a surface such as a wheel, wheel cover or tire. For automotive surfaces, the application of this film substantially reduces or eliminates the need for harsh acidic, caustic or solvent-borne cleaners to maintain wheel and tire appearance. This now offers consumers the ability to treat a wheel and tire once with a repellant film to maintain its appearance. Consumers can deliver the films from aerosol or trigger spray packages, gels or pre-saturated wipes.
[0006] According to one aspect of the present invention a sprayable, liquid polymeric film-forming composition is provided containing an amount of anti-static polymer that is effective to provide films formed from the composition with resistance to the deposition of dust, soil or grime on the surface thereof, wherein the surface tension of the liquid composition is less than 25 milli-newtons per meter. The low surface tension of the liquid composition provides the polymer films formed therefrom with a low surface energy that contributes to the dust, soil and grime resistance.
[0009] (A) Anti-static polymers that also contribute to lowering the surface tension of the liquid compositions, thereby lowering the surface energy of the polymeric films;
[0014] Compositions according to the present invention may optionally include a substantiative polymer providing water resistance to the polymeric film. Water resistance increases the durability of the films.
[0016] According to another aspect of the present invention, a method is provided for preventing the accumulation of dust, soil or grime on a surface by applying a composition according to the present invention thereto so that a polymeric film coating is formed thereon resistant to the deposition of soil, dust and grime. The composition coating is left on the surface as a protective polymeric film. The composition may be applied to the surface by means of aerosol or trigger spray device, as a gel, or from a pre-saturated wipe.
[0017] Examples of some of the surfaces included within the method of the present invention include automotive surfaces, such as engine components and vehicle tires, wheels or wheel covers; optical surfaces, for which dust is a particular problem; the surface of product packages, including retail product packaging, to maintain product appearance regardless of storage duration or conditions; and household surfaces, such as furniture, floors, walls, and the like, to reduce the frequency with which such surfaces must be cleaned.

Problems solved by technology

The extremely low pH of these formulations makes their compatibility poor with many metallic wheels and most of these products are devised for use on clear-coated wheels so there is no (or very low) chance of acid corrosion.
This composition has the disadvantage of low pH and the use of fluoride salts which may be detrimental to the environment and human safety.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0044] A brake dust repellant composition was prepared containing the following components:

TABLE IWEIGHTCHEMICALPERCENTCOMMERCIAL NAMEDESCRIPTION0.20Lambent MFF 199silicone copolyol10.0L31 fluid (Crompton)methyl hydrogen siloxane1.0Triton W30anionic emulsifier0.50Triton TMN-6non-ionic emulsifierAcetic acid to pH 4-5

[0045] The silicone copolyol, manufactured by Petroferm of Feranandina Beach, Fla., functions as a wetting agent. The methyl hydrogen siloxane functions as an anti-static agent. The two emulsifiers were combined and then blended with the methyl hydrogen siloxane and silicone copolyol. The mixture was then blended with 88.3 weight percent water adjusted with acetic acid below pH 6. This blend was then homogenized to form a stable emulsion, which was further adjusted with acetic acid to pH 4-5. The surface tension of the composition was measured and determined to be 22 milli-newtons per meter.

example 2

[0046] A brake dust repellant composition was prepared containing the following components:

TABLE IIWEIGHTCHEMICALPERCENTCOMMERCIAL NAMEDESCRIPTION0.50Zonyl FSK (Dupont)Amphoteric Fluorocarbon0.50Lambent CSI-DT (Petroferm)Silicone Carboxylate0.80Avalure AC-115 (Noveon)Acrylate CopolymerAmmonium Hydroxide topH 9

[0047] The amphoteric fluorocarbon functions as an anti-static agent. It also contributes to surface tension reduction and surface wetting. The silicone carboxylate functions as a wetting agent. The acrylate copolymer contributes substantivity and surface adhesion to the polymeric film.

[0048] The composition was prepared by adjusting 98.2 weight percent water to pH 9 with ammonium hydroxide. The acrylate copolymer was then dissolved after which the amphoteric fluorocarbon and silicone carboxylate were then dissolved in the solution. The pH was checked and adjusted again to 9 using ammonium hydroxide. The surface tension of the composition was measured and determined to be 19...

example 3

[0049] A brake dust repellant composition was prepared using the following components:

TABLE IIIWEIGHTCHEMICALPERCENTCOMMERCIAL NAMEDESCRIPTION0.60PA 10 (Essential Ingredients)Anionic fluorocarbon0.80Avalure AC-i 15 (Noveon)Acrylate copolymer0.50Lambent WS-100 (Petroferm)Silicone sulfateAmmonium Hydroxide pH 9

[0050] The anionic fluorocarbon functions as an anti-static agent and contributes to surface wetting and surface tension reduction. The silicone sulfate functions as a wetting agent. The acrylate copolymer functions to promote substrate adhesion and substantivity. The components were combined to form an aqueous solution as in Example 2. The solution surface tension was measured at 20 milli-newtons per meter.

EVALUATION

[0051] The front wheels of test vehicles with known brake dust deposition problems were coated with the compositions of Examples 1-3 using a trigger sprayer (Calmar). The color (amount of soil) of the treated areas was rated biweekly by four observers. The ratin...

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Abstract

Sprayable, liquid polymeric film-forming compositions containing an amount of an anti-static polymer that is effective to provide films formed from the composition with resistance to the deposition of dust, soil or grime on the surface thereof, wherein the surface tension of the liquid composition is less than about 25 milli-newtons per meter. Methods for preventing the accumulation of dust, soil, or grime on surfaces such as a vehicle tire, wheel or wheel cover are also disclosed.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a method of coating surfaces with a low surface energy anti-static film that repels dust, soil and grime in a manner that is suitable for use by a typical consumer. This invention also relates to compositions for use by consumers to repel dust, soil and grime from surfaces. The invention more particularly relates to methods and compositions for repelling dust soil and grime, and in particular brake dust, from the surface of vehicle wheel and wheel covers. BACKGROUND OF THE INVENTION [0002] A wide variety of automobile appearance products are used in consumer applications to maintain the original appearance of automobiles. Specifically, numerous wheel and tire cleaners are commercially available to maintain the appearance of soiled tires and metal or plastic wheels, wheel covers or hubcaps. These tire cleaners are typically acidic formulations, with pH ranges from 2 to 4. The extreme acidity is required to effectively rem...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): D06M13/224B05D5/06B05D3/02B05D5/08C09D5/00C09D201/00C09K3/16C09K3/22
CPCB05D5/08C09D5/00C09K3/22C09K3/16C09D201/00
Inventor SHANNON, CHRISTOPHERHAYES, STEVE
Owner PETROFERM INC
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