The invention discloses a laundry material which is characterized by comprising the components of nanometer anion powder, 4A zeolite, photocatalyst, an anion surface active material, a high polymer bonding material, a high polymer curing material and auxiliary materials. The invention also discloses a preparation method of the laundry material and a laundry ball with the laundry material. The laundry material not only can reduce the pollution to water sources, but also has the health-care functions of clothes cleaning, antisepsis, mildew proofing, air purification, deodorization, fatigue dissipation, and the like. The invention can be widely used for the washing industry, has good cleaning effect, strong function and no damage to the skin of the human body, can be circularly used for washing for multiple times, saves water, electricity and energy and belongs to a novel international washing article.