The invention belongs to the field of 3D printing fused deposition modeling, and discloses a multi-material synchronous fed FDM spray head. The spray head comprises a feeding unit, a mixing chamber, apneumatic extrusion unit and a nozzle, wherein materials enter the mixing chamber from the feeding unit, then are stirred and uniformly mixed, enter the nozzle under the action of the pneumatic extrusion unit and are extruded; and the feeding unit comprises a plurality of feeding ports, each feeding port is provided with a funnel, an upper pneumatic butterfly valve, a transition bin and a lower pneumatic butterfly valve, after the materials are added into the funnels, the upper pneumatic butterfly valves are opened to enable the materials to enter the transition bins, then the lower pneumaticbutterfly valves are opened to enable the materials to enter the mixing chamber, in the process, the upper pneumatic butterfly valves and the lower pneumatic butterfly valves are opened separately step by step, so that external gas is prevented from entering the mixing chamber, air pressure in the mixing chamber is ensured, and meanwhile the materials in the mixing chamber are prevented from being oxidized. According to the spray head, extrusion forming of complex parts including different types and different gradient materials is realized, the forming time is shortened, and the forming efficiency and the forming precision are improved.