Recording ink, ink cartridge, ink record, inkjet recording apparatus and inkjet recording process
A technology for recording inks and polymers, applied in the direction of reproduction/marking methods, inks, printing, etc., can solve the problems of undisclosed or implied ordinary paper performance, poor weather resistance and water resistance, and achieve excellent color development performance and high Delivery stability, color saturation improvement effect
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preparation Embodiment 1
[0232] -Preparation of Polymer Microparticle Dispersions Including Copper Phthalocyanine Pigments-
[0233] A 1 L flask equipped with a mechanical stirrer, thermometer, reflux tube, and dropping funnel was fully purged with nitrogen, and 11.2 g of styrene, 2.8 g of acrylic acid, 12.0 g of lauryl methacrylate, 4.0 g of polymethylmethacrylate were added to the flask. ethylene glycol acrylate, 4.0 g of styrene macromonomer (manufactured and sold by ToaGosei Co., Ltd.; trade name: AS-6) and 0.4 g of mercaptoethanol, followed by heating the flask at a temperature of 65°C. Next, within 25 hours, 100.8 grams of styrene, 25.2 grams of acrylic acid, 108.0 grams of lauryl methacrylate, 36.0 grams of poly(ethylene glycol methacrylate), 60.0 grams of hydroxyethyl methacrylate, 36.0 grams of styrene Molecular monomer (manufactured and sold by Toa Gosei Co., Ltd.; trade name: AS-6), 3.6 g of mercaptoethanol, 2.4 g of azobisdimethylvalelonitrile, and 18 g of methyl ethyl ketone The first mi...
preparation Embodiment 2
[0238] -Preparation of Polymer Microparticle Dispersions Including Dimethylquinacridone Pigments-
[0239] A magenta polymer microparticle dispersion was prepared substantially in the same manner as in Preparation Example 1 except that the copper phthalocyanine pigment was replaced by the pigment "Pigment Red 122".
[0240] The average particle diameter of the obtained polymer microparticles was measured using a particle size distribution measuring instrument (manufactured and sold by Nikkiso Co., Ltd.; trade name: Microtrack UPA), and the average particle diameter (D50%) was found to be 127 nm.
preparation Embodiment 3
[0242] -Preparation of Polymer Microparticle Dispersion Including Monoazo Yellow Pigment-
[0243] A yellow polymer microparticle dispersion was prepared substantially in the same manner as in Preparation Example 1 except that the copper phthalocyanine pigment was replaced by the pigment "Pigment Yellow 74".
[0244] The average particle diameter of the obtained polymer microparticles was measured using a particle size distribution measuring instrument (manufactured and sold by Nikkiso Co., Ltd.; trade name: Microtrack UPA), and found to be 76 nm in average particle diameter (D50%).
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