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Method for preparing nontoxic coloured silicasol

A silica sol and colored technology, which is applied in the field of preparation of non-toxic colored silica sol, can solve the problems of inability to colorize, and the application of coloring cannot meet the requirements, and achieves the effects of strong colorability, stable properties and convenient operation.

Inactive Publication Date: 2008-05-14
国家复合改性聚合物材料工程技术研究中心
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The patent application number is 200610155112.x, and the patent application titled "a preparation method of monodisperse silica sol" discloses a preparation method of silica sol, which uses silicon powder under the action of heating and catalyst Dissolved in deionized water to prepare silica sol, but because it is dissolved in deionized water, the obtained silica sol is colorless, which cannot meet the demand in applications that require coloring
[0003] The existing silica sol itself is colorless and transparent, although it does not affect the covered object in use, but in the occasion where color is required, the existing silica sol products have the defect that they cannot be colored

Method used

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Embodiment Construction

[0028] Preferred embodiment of the present invention: Add 0.25 kg of elemental silicon powder with a particle size of 200 mesh and 20 grams of catalyst in 3.5 kg of deionized water, heat to 90 ° C, stir at a constant speed of 100 rpm, and drop the concentration of 28% every two hours 5ml of ammonia water, stop dripping ammonia water after four hours, and colorless silica sol is obtained. Adjust the pH of the colorless silica sol to 2-4 with a 5% hydrochloric acid solution, and then add FeCl with a molar concentration of 0.3mol / l 3 0.2 kg of aqueous solution, continue to heat and stir for 8 hours, filter, stir and concentrate at 150°C until the solution concentration is 15-20%, that is, a non-toxic colored silica sol is obtained.

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PUM

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Abstract

The invention provides a preparation method for nontoxic colored silica sol, which comprises the following steps: firstly, the colorless silica sol is prepared, and the pH of the colorless silica sol is adjusted into neutral, and then the colorless silica sol is mixed with the nontoxic colored metal ionized water solution; the pH value of the mixture is adjusted to 2 to 4, and the mixture is reacted for 6 to 10 hours under the conditions of heating and stirring, and then is filtered and concentrated for producing the nontoxic colored silica sol. The invention overcomes the shortcomings of colorlessness and transparence existing in the prior silica sol; the nontoxic colored metallic particles are adopted to make the generative silica sol be colorful during the process of preparing the silica sol with silicon dissolution method. The granularity of the prepared silica sol is 5 to 37nm. The silica sol which is prepared with the method of the invention has the advantages of stable quality, innocuity, bright color and strong colouration, thereby the invention can be widely used in preparing nontoxic colored medical equipment, food package film and other products.

Description

technical field [0001] The invention relates to a preparation method of silica sol, in particular to a preparation method of nontoxic colored silica sol. Background technique [0002] Silica sol is a colloidal solution of polymer silica particles dispersed in water or organic solvents. It is odorless and non-toxic, and its appearance is mostly milky white or light blue transparent solution. Silica sol has many excellent properties, such as greater adsorption, better cohesiveness, good temperature resistance, "high dispersibility", "good wear resistance" and good " Translucency", etc., so it can be used as a good "dispersant", "preservative", "flocculant", "coolant" and special "optical material". At present, silica sol has been widely used in fiber, fabric, paper, rubber, coating, paint, ceramics, refractory coating, floor wax and other industries. In addition, it is also used in the polishing of semiconductor silicon wafers, water treatment, mineral flotation and beer, wi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B33/141
Inventor 于杰蒋冠森鲁圣军何敏罗筑周秉正都佩华
Owner 国家复合改性聚合物材料工程技术研究中心
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