Low-electric-conductivity and gray track resistant Rb:KTP crystal and method for preparing same
A low-conductivity, anti-ashing technology, applied in crystal growth, chemical instruments and methods, self-solidification methods, etc., can solve problems such as loss of function, KTP crystal device damage, etc., to achieve stable absorption coefficient and good anti-ashing performance Effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0025] The embodiment of the present invention provides a kind of low electrical conductivity, anti-ash trace Rb:KTP crystal, the chemical formula of this crystal is Rb x K (1-x) TiOPO 4 , 0.01+ By Rb + Except for substitution, its unit cell structure is basically the same as ordinary KTP.
[0026] to normal K 6 P 4 o 13 (hereinafter referred to as K6) KTiOPO of flux system 4 (hereinafter referred to as KTP) growth was modified by doping, and the Rb + 、Cs + , Ga 3+ 、Al 3+ Doping modification experiments with various ions, and found that Rb + Doping modification also has the characteristics of low conductivity in the Z direction and good anti-blue-green gray staining effect. Further experiments show that Rb + Effect of doping content on crystal properties, final determination of low Rb + The doping content has the most significant improvement on the gray stain resistance of KTP crystals. Rb + As an alternative ion to replace part of K in KTP + position, due to th...
Embodiment 2
[0030] Embodiments of the present invention provide a method for preparing low-conductivity, anti-ash stain Rb:KTP crystals, comprising the following steps:
[0031]1) Add rubidium carbonate to the raw material system of growing KTP with K6 as flux and stir evenly to make Rb:KTP crystal raw material;
[0032] The specific steps are:
[0033] Add rubidium carbonate to the mixture of potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate and stir well. The potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate are added in a ratio of 1.345:1 (this is the optimal ratio) after the reaction to form KTP and K6 molar ratio. The rubidium carbonate is added in a ratio of 1% by weight to the mixture of potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate.
[0034] 2) Put the made Rb:KTP crystal raw material into a platinum or gold crucible for heating and melting and then cool down to the saturati...
Embodiment 3
[0056] Embodiments of the present invention provide a method for preparing low-conductivity, anti-ash stain Rb:KTP crystals, comprising the following steps:
[0057] 1) Add rubidium carbonate to the raw material system of growing KTP with K6 as flux and stir evenly to make Rb:KTP crystal raw material;
[0058] The specific steps are:
[0059] Add rubidium carbonate to the mixture of potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate and stir well. The potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate are added according to the molar ratio of KTP and K6 formed after the reaction is 1.186:1. The rubidium carbonate is added in a ratio of 2.7% by weight to the mixture of potassium dihydrogen phosphate, titanium dioxide and dipotassium hydrogen phosphate.
[0060] 2) Put the made Rb:KTP crystal raw material into a platinum or gold crucible for heating and melting and then cool down to the saturation point;
[006...
PUM
Login to View More Abstract
Description
Claims
Application Information
Login to View More