Polyester alloy
A polyester alloy and pairing technology, applied in the field of polyester alloys, can solve the problems of phase separation and large differences in solubility parameters, and achieve the effect of reducing dosage and high utilization value.
Inactive Publication Date: 2014-02-12
TORAY FIBER RES INST(CHINA) CO LTD
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- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
However, due to the large difference in the solubility parameters of the two, simple blending is prone to phase separation.
Method used
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Experimental program
Comparison scheme
Effect test
Embodiment 1
[0035] Add 100g of poly-L lactic acid, 900g of PET resin, and 10g of compatibilizer PMBG to blend and granulate. Wherein the weight-average molecular weight of PMBG is 87400, and the epoxy equivalent is 1100g / eq.
Embodiment 2
[0037] Add 100g of poly-L lactic acid, 900g of PET resin, and 30g of compatibilizer PMBG to blend and granulate, wherein the weight average molecular weight of PMBG is 87400, and the epoxy equivalent is 1100g / eq.
Embodiment 3
[0039] Add 300g of poly-L lactic acid, 700g of PET resin, and 10g of compatibilizer PMBG to blend and granulate. Wherein the weight-average molecular weight of PMBG is 30913, and the epoxy equivalent is 470g / eq.
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Abstract
The invention discloses a blended resin composition. Based on the total weight of 100 percent, the resin composition is formed mainly by blending 60 to 99 weight parts of aromatic polyesters and 40 to 1 weight part of aliphatic polyesters. In addition, the resin composition also contains a compatibilizer in an amount of 0.5 to 10 percent based on the total weight of the composition, wherein the compatibilizer is obtained by polymerizing active epoxy group-containing olefine acid esters. In the blended resin composition, the aliphatic polyesters serving as a disperse phase are dispersed in the aromatic polyesters serving as a continuous phase, and have the mean grain size of less than 600 nm. The resin composition provided by the invention can keep the heat resistance of conventional polyesters and reduce the using amounts of petrochemical raw materials, is applied to apparel fibers, optical thin films, various moldings, outer plate parts of buffer bars, doors and the like of automobiles, structural parts of the automobiles, and the like, and compared with the conventional polyesters, produces lower environmental load and has high utilization value.
Description
technical field [0001] The invention belongs to the field of macromolecular materials, and specifically relates to a polyester alloy obtained by compounding aromatic polyesters and aliphatic polyesters in the presence of a compatibilizer through physical compatibility and / or chemical combination. Background technique [0002] Aromatic polyesters such as polyethylene terephthalate (PET), polytrimethylene terephthalate (PTT), polybutylene terephthalate (PBT), etc., have good chemical stability , processability, heat resistance, and dimensional stability, and are widely used in the fields of fibers, films, and molding materials. [0003] The main raw materials of aromatic polyesters, such as terephthalic acid, ethylene glycol, 1,3-propanediol, 1,4-butanediol, etc., are mainly synthesized from petroleum-derived raw materials through chemical reactions. As aromatic polyester is a kind of petrochemical material, it has extremely high hydrolytic stability under normal circumstance...
Claims
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IPC IPC(8): C08L67/02C08L67/04C08L33/14C08L51/06C08L53/00
Inventor 陆榕欧阳芬吴刚
Owner TORAY FIBER RES INST(CHINA) CO LTD
