Linear ion trap analyzer
An ion trap and analyzer technology, applied in the direction of mass spectrometer, etc., can solve the problems of field adjustment electrode setting and voltage application difficulty, increasing instrument cost, etc.
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no. 1 example
[0037] still refer to figure 1 An example of the present invention will be described. The structure of the two-dimensional linear ion trap is divided into front section 4, middle section 5 and back section 6. The front and back sections 4 and 6 are provided with relatively high potentials to generate axial constraints on ions (for positive ions, it is relatively high for negative ions). low potential, the same hereinafter). Each section has two pairs of main electrodes 1 and 2 in the X and Y directions, on which driving high-frequency voltages in opposite phases are applied to form a radial trapping electric field. In an alternative embodiment, the front section 4 and the rear section 6 can also be replaced by front and rear end cap electrodes, so as to generate a DC or AC trapped electric field in the axial direction. Ions are usually introduced from one end along the Z axis and are trapped in a linear region between two pairs of electrodes along the X and Y axes. If a dip...
no. 2 example
[0044] As mentioned above, planar electrodes, as a special case of cylindrical electrodes, can also be used to form linear ion traps. image 3 A schematic diagram of a rectangular linear ion trap built with four planar electrodes according to the second embodiment of the present invention is given. For clarity and brevity, image 3 Only the middle section is shown, and the front and rear sections or end caps are omitted. refer to image 3 As shown, the two pairs of main electrodes 11 and 12 in the X and Y directions respectively apply driving high-frequency voltages in opposite phases to form a radial trapping electric field. In the middle of the X electrodes 11a opposite to the lead-out slots 13, a field regulating electrode 15 is provided. Similar to the first embodiment, the voltage on the field adjusting electrode is set to be the high-frequency voltage V on the adjacent X electrode 11a 1a at least part of and a DC voltage V DC superposition, that is:
[0045] V fae...
no. 3 example
[0049] In this embodiment, in order to obtain a better quadrupole field shape for the rectangular linear ion trap built with planar electrodes, each electrode plane can be composed of several sub-electrodes, and each sub-electrode is added with a certain proportion of high-frequency Voltage, forming a field shape similar to the electric field generated by a hyperbolic cylinder. The specific details of this type of ion trap can be referred to in Chinese patent CN1585081.
[0050] Figure 4 A cross-sectional structure of a planar printed circuit (PCB) type linear ion trap according to this embodiment is shown. In this embodiment, a planar strip-shaped printed circuit 26 is provided on at least a part of the electrode plates, and a field regulating electrode 25 is provided in the middle of the X electrode plate 21 opposite to the lead-out groove 23 . Wherein, the field adjusting electrode 25 with trapezoidal cross-section can be retracted into the interior of the adjacent X ele...
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