High solid content acrylic varnish, and preparation method and application thereof

An acrylic varnish, high solid content technology, applied in the direction of coating, etc., can solve the problems of low degree of cross-linking, physical injury, chemical migration resistance of the paint film, etc., to improve impact resistance and adhesion, enhance network Mature and stable effect of structure and production process

Inactive Publication Date: 2012-05-09
CARPOLY CHEM GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] On the one hand, traditional tableware coatings often use toxic toluene, cyclohexanone, isocyanate and other high paint residues; The migration of the paint or the formaldehyde and phthalates in the bamboo and wood manufacturing process gradually migrates into the food. Once people eat these contaminated foods by mistake, they will cause serious harm to the body.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0057] A kind of high solid content acrylic varnish, its raw material composition and mass percentage composition are as shown in table 1:

[0058] Table 1

[0059] raw material

Dosage (% mass)

Hydroxyacrylate Resin

60

Bayer N3390

10

Bayer L-75

15

acetone

4

Butyl acetate

4

Dimethyl carbonate

4.6

Tego-245

1

F40

0.7

TEGO-936

0.7

[0060] Wherein the hydroxyacrylic resin raw material composition and mass percentage composition are as shown in Table 2:

[0061] Table 2

[0062] raw material

Dosage (% mass)

Methyl methacrylate

20

Butyl acrylate

17.5

acrylic

2.5

Hydroxyethyl Acrylate

5

Hydroxypropyl Acrylate

5

Dibenzoyl peroxide

2.5

dodecyl mercaptan

0.35

acetone

15

Butyl acetate

15

Dimethyl carbonate

...

Embodiment 2

[0076] A kind of high solid content acrylic varnish, its raw material composition and mass percentage composition are as shown in table 3:

[0077] table 3

[0078] raw material

Dosage (% mass)

Hydroxyacrylate Resin

60

Bayer N3390

20

acetone

6

Butyl acetate

6

Dimethyl carbonate

5.6

Tego-245

1

F40

0.7

TEGO-936

0.7

[0079] Wherein the hydroxyl acrylic resin raw material composition and mass percentage composition are as shown in table 4:

[0080] Table 4

[0081] raw material

Dosage (% mass)

Methyl methacrylate

26.3

Butyl acrylate

18.7

acrylic

3

Hydroxyethyl Acrylate

7.1

Hydroxypropyl Acrylate

4.9

methyl ethyl ketone peroxide

2.5

dodecyl mercaptan

0.35

acetone

13

Butyl acetate

12

Dimethyl carbonate

12.15

...

Embodiment 3

[0095] A kind of high solid content acrylic varnish, its raw material composition and mass percentage composition are as shown in table 5:

[0096] table 5

[0097] raw material

Dosage (% mass)

Hydroxyacrylate Resin

50

Bayer L-75

30

acetone

6

Butyl acetate

6

Dimethyl carbonate

6

BYK-103

1

BYK-306

0.5

BYK-141

0.5

[0098] Wherein the hydroxyacrylic resin raw material composition and mass percentage content are as shown in table 6:

[0099] Table 6

[0100] raw material

Dosage (% mass)

Methyl methacrylate

10.6

Butyl acrylate

14.2

n-Propyl Acrylate

7

acrylic

3.5

Hydroxyethyl Acrylate

14.2

Hydroxypropyl Methacrylate

10.5

cyclohexanone peroxide

3

dithioester

0.7

acetone

12

Butyl acetate

12

Dimethyl carbonate...

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PUM

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Abstract

The invention discloses a high solid content acrylic varnish which comprises the following raw materials in percentage by mass: 50-60% of hydroxy acrylic resin, 20-30% of polyurethane curing agent, 12.6-18% of organic solvent, 0.1-2% of wetting agent, 0.1-2% of flatting agent and 0.1-1% of antifoaming agent. The high solid content acrylic varnish disclosed by the invention can be applied in bamboo and wood tableware, is combined with a high solid content coating technology and technologies of cross-linked film curing and organic solvent removal and is a new development direction for bamboo and wood coatings and coating materials.

Description

technical field [0001] The invention relates to the field of coatings, in particular to an acrylic varnish with high solid content and its preparation method and application. Background technique [0002] There are many kinds of bamboo and wood products in contact with food, which can be divided into containers, such as barrels, cans, boxes, bowls, plates, baskets, steamers, etc.; Cork, sushi rolls, etc.; packaging, such as boxes, etc.; are one of the indispensable daily necessities in people's lives. Materials in contact with food must meet the following conditions: when in contact with food, they must not release substances that are dangerous or harmful to human health; they must not cause unacceptable changes in the composition of food; such as changes in taste, smell, color, etc. of food). [0003] Since the reform and opening up, my country's bamboo and wood products industry has achieved great development, and now it has become the world's largest producer and export...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/12C09D133/08C09D133/14C08F220/14C08F220/18C08F220/28C08F2/38
Inventor 冯钦叶代勇郑振杰
Owner CARPOLY CHEM GRP
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