Preparation method of high-impact-resistance solid buoyancy material

A solid buoyancy, high impact technology, applied in the field of solid buoyancy materials, can solve the problems of reducing the compression resistance of materials, being susceptible to collision and impact, and increasing construction technology.

Inactive Publication Date: 2013-06-26
SHANGHAI MARITIME UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, solid buoyant materials are prone to collision and impact during handling, installation and use after production, so the impact resistance of the material needs to be improved
Invention patent CN02135509.6 "Spray polyurea coating for solid buoyancy materials" uses the method of spraying polyurea coating to improve the impact resistance of materials. Although this method is simple, it needs to increase the construction process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Get bisphenol A type epoxy resin E51-100 parts, hollow glass microspheres K37-80 parts, coupling agent KH550-1 part, toughening agent-irradiation cross-linking graft modified ultra-high molecular weight polyethylene 10 parts, Put it into a vacuum mixer and stir in vacuum at 80°C for 10 minutes; 80 parts of curing agent methyltetrahydrophthalic anhydride and catalyst N,N-dimethylbenzylamine are stirred in vacuum at 60°C for 10 minutes; Stir in a vacuum blender for 10 minutes. The mixture is poured into male and female molds and molded under a pressure of 20MPa. The curing system is 110°C / 2h+140°C / 6h+160°C / 4h. The solid buoyancy material can be obtained after demolding, and the material can be processed into devices of various shapes through lathing. The obtained material is tested by the US military standard MIL-S-24154A to obtain a density of 0.45g / cm 3 , Anti-hydrostatic pressure 25MPa, divided by 1.5 coefficient is 16.7MPa, the material can be used in water depths w...

Embodiment 2

[0026] Get bisphenol A epoxy resin E51-100 parts, hollow glass microspheres K46-100 parts, coupling agent KH550-0.5 parts, toughening agent-radiation cross-linking graft modified ultra-high molecular weight polyethylene 15 parts, Put it into a vacuum mixer and stir in vacuum at 80°C for 10 minutes; 80 parts of curing agent methyltetrahydrophthalic anhydride and catalyst N,N-dimethylbenzylamine are stirred in vacuum at 60°C for 10 minutes; Stir in a vacuum blender for 10 minutes. The mixture is poured into male and female molds and molded under a pressure of 20MPa. The curing system is 110°C / 2h+140°C / 6h+160°C / 4h. The solid buoyancy material can be obtained after demolding, and the material can be processed into devices of various shapes through lathing. The obtained material is tested by the US military standard MIL-S-24154A to obtain a density of 0.56g / cm 3 , Anti-hydrostatic pressure 46MPa, divided by 1.5 coefficient is 30.7MPa, the material can be used in water depths with...

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Abstract

The invention provides a preparation method of a high-impact-resistance solid buoyancy material. The high-impact solid buoyancy material disclosed by the invention improves the impact resistance of the solid buoyancy material by using irradiation-crosslinked maleic anhydride grafted ultrahigh-molecular weight polyethylene micrometer particles as a flexibilizer. An impact-resisting modifying agent, together with epoxy resin, a curing agent, a catalyst, a coupling agent and hollow glass beads, is processed to prepare the high-impact-resistance solid buoyancy material. The two prepared solid buoyancy materials can be suitable for sea depths of 1000 m and 3000 m, and the impact strength is increased by 60% or higher than that before adding the impact-resisting modifying agent. The invention further provides a preparation method of the high-impact-resistance solid buoyancy material.

Description

technical field [0001] The invention relates to a solid buoyancy material with high impact strength, in particular to a solid buoyancy material with high impact strength suitable for providing buoyancy for marine development equipment such as offshore oil exploitation risers and underwater operation submersibles. Background technique [0002] The solid buoyancy material technology organically combines the low-density and high-strength properties of the material, making it incomparably superior in the field of ocean development technology. Solid buoyancy materials have been applied to (1) deep-sea transportation and operation equipment such as China's "Jiaolong" 7000m deep submersible, China's "CR-02" self-made underwater robot, (2) offshore oil exploitation systems Such as risers, oil pipelines, (3) marine survey and detection systems such as submersible marking systems, (4) marine mining systems such as seabed mining machines and other fields. The solid buoyancy material m...

Claims

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Application Information

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IPC IPC(8): C08L63/02C08L63/04C08L63/00C08L51/06C08K7/28C08J3/28C08J3/24C08F255/02C08L23/06
Inventor 董丽华尹衍升吴新锋张福华李晓峰周云
Owner SHANGHAI MARITIME UNIVERSITY
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