System designed to reduce the amount of nox in motor vehicle exhaust gases
A technology for exhaust gas and motor vehicles, used in exhaust treatment, exhaust equipment, machines/engines, etc.
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[0029] In the proposed system, the storage of reducing agent is based on the reversible solid-gas reaction type:
[0030]
[0031] Where the gas is ammonia and the solid is an anhydrous salt of the metal chloride type: MgCl 2 , SrCl 2 , CaCl 2 , BaCl 2 , ZnCl 2 Wait.
[0032] The uptake (i) and desorption (ii) reactions are fully reversible. The ammonia equilibrium pressure of the system can be determined by the Clausius-Clapeyron equation for a given temperature given by:
[0033] ln P NH 3 = - ΔHr RT + ΔSr R
[0034] where ΔHr is per mole of NH 3 The desorption enthalpy, ΔSr per mole of NH 3 The desorption entropy, R is the ideal gas constant.
[0035] According to this formula, the ammonia equilibrium pressure of these salts depends on the temperature.
[0036] A...
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