A kind of environment-friendly additive type polyethylene flame retardant masterbatch and preparation method thereof

A flame retardant masterbatch, polyethylene technology, applied in the field of polymer materials, can solve the problems of component fluctuation, limited mixing, poor flammability, etc., achieve small impact on mechanical properties, improve market competitiveness, and excellent processing performance Effect

Active Publication Date: 2015-11-04
GUANGDONG JUSHI CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Due to its excellent performance, polyethylene (PE) is widely used in chemical industry, agriculture, construction, packaging and other fields, but its flammability is poor, and the product has fire hazards, so it is necessary to modify its flame retardancy
In order to improve the flame retardancy of polyethylene materials, people usually add flame retardants to the raw materials for production. However, most of the flame retardants are powders. The volume difference between the body and the resin substrate is large, the density difference is huge, and the raw materials are difficult to mix evenly
In addition, extruders and injection molding machines have limited mixing of materials along the axial center and equipment vibration, which makes the powder easily sink and cause separation from the resin substrate, resulting in segregation
In addition, the powder is easy to agglomerate, which also makes the feeding inaccurate, resulting in component fluctuations, unstable material properties, and it is difficult to achieve the expected flame retardant effect.
In the prior art, the problem of poor operating environment is solved by preparing flame-retardant masterbatches, but the flame-retardant masterbatches in the prior art have the disadvantages of poor product dispersibility, difficult processing, toxicity, poor flame-retardant performance or high price. Inability to meet customer needs

Method used

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  • A kind of environment-friendly additive type polyethylene flame retardant masterbatch and preparation method thereof

Examples

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Comparison scheme
Effect test

Embodiment 1

[0030] Example 1 is the preparation method of the environmentally friendly added polyethylene flame retardant masterbatch of the present invention, and Examples 2 and 3 are polyethylene flame retardant materials prepared by using the environmentally friendly added polyethylene flame retardant masterbatch obtained in Example 1. Comparative example 1 and 2 are polyethylene flame retardant materials prepared with powder flame retardants.

[0031] Example 1

[0032]A preparation method of environmentally friendly polyethylene flame-retardant masterbatch, the preparation method comprising steps: 1) weighing 10 parts of carrier resin, 15 parts of chlorinated polyethylene, 28 parts of decabromodiphenylethane, three 10 parts of antimony oxide, 3~10 parts of TBC flame retardant, 12 parts of flame retardant synergist, 5~15 parts of MCA flame retardant, 8 parts of lubricant and 1 part of antioxidant, and use a high-speed mixer to stir the materials for 3 minutes ;2) Pass the mixed mater...

Embodiment 2

[0034] The polyethylene flame retardant material in this example is obtained by mixing the following parts by weight: 90.5 parts of low density polyethylene 2420H (LDPE 2420H), 9 parts of flame retardant masterbatch, and 0.5 part of lubricant.

Embodiment 3

[0036] The polyethylene flame retardant material in this embodiment is obtained by mixing the following parts by weight: 83.5 parts of high density polyethylene HMA035 (HDPE HMA035), 16 parts of flame retardant masterbatch, and 0.5 part of lubricant.

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Abstract

The invention discloses an environment-friendly adding type polyethylene flame-retardant masterbatch. The masterbatch comprises the following raw materials by mass: 10 parts of carrier resin, 15 parts of chlorinated polyethylene, 28 parts of decabromodiphenylethane, 10 parts of antimony trioxide, 3-10 parts of TBC (tri-N-butyl citrate) flame retardant, 12 parts of flame retardant synergist, 5-15 parts of MCA (melamine cyanurate) flame retardant, 8 parts of lubricating agent and 1 part of antioxidant. The polyethylene flame-retardant masterbatch is environment-friendly, non-toxic, clean and sanitary. The flame retardant efficiency is obvious; the processing performance is excellent; when the masterbatch is used for producing polyethylene products, the addition is low, so that the production cost for the polyethylene material can be greatly reduced; the polyethylene flame-retardant masterbatch is suitable for development of enterprises.

Description

technical field [0001] The invention relates to the field of polymer materials, in particular to an environmentally friendly flame-retardant polyethylene masterbatch, and also relates to a preparation method of the environmentally friendly added polyethylene flame-retardant masterbatch. Background technique [0002] Polyethylene (PE) is widely used in chemical industry, agriculture, construction, packaging and other fields due to its excellent performance, but its flammability is poor, and the product has fire hazards. Therefore, it is necessary to modify its flame retardancy. In order to improve the flame retardancy of polyethylene materials, people usually add flame retardants to the raw materials for production. However, most of the flame retardants are powders. The volume difference between the body and the resin substrate is large, and the density difference is huge, so it is difficult to mix the raw materials evenly. In addition, extruders and injection molding machin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/28C08L23/08C08K13/06C08K9/00C08K5/03C08K3/22C08K5/3492C08J3/22
CPCB29B9/06B29C48/92B29C2948/92619B29C2948/92704C08J3/226C08J2323/06C08J2423/08C08J2423/28C08K2201/003C08K2201/014C08L23/06C08L23/286C08L2201/02C08L23/0815C08L23/0853C08L2205/03C08K13/06C08K9/00C08K5/03C08K3/2279C08K5/34924C08L2205/035C08L2207/066C08L2207/062
Inventor 沈旭渠张翼翔梁发雄沈寒知姚杏梅
Owner GUANGDONG JUSHI CHEM CO LTD
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