Preparation method of polypropylene type bonding resin for multi-layer coextrusion barrier packaging

A polypropylene-type, multi-layer co-extrusion technology, applied in lamination devices, chemical instruments and methods, lamination, etc., can solve the problem of excessive tensile stress and strain of bonding strength, affecting product quality and production efficiency, and angular edges Solve problems such as delamination, achieve excellent bonding performance, improve product quality and production efficiency, and achieve lasting and stable bonding strength

Active Publication Date: 2015-02-25
HEYUAN PLG MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the bonding strength is not enough, the co-extruded film will delaminate during the production of multi-layer co-extruded film or when stretched and packaged by vacuum, which seriously affects product quality and production efficiency
At present, when using polypropylene multi-layer co-extrusion film or polyethylene multi-layer co-extrusion film to package angular products (such as trotters, beef steaks, and electronic printed circuit boards, etc.), the corners and corners will be damaged when they pass through the vacuum stretching process. Delamination often occurs at the edge, indicating that the bonding strength of the adhesive resin at the edge of the edge is severely reduced or lost due to the relative excessive tensile stress and strain between the layers during vacuum stretching. Therefore, in the prior art The use of polypropylene-type bonding resins and polyethylene-type bonding resins imposes higher requirements

Method used

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  • Preparation method of polypropylene type bonding resin for multi-layer coextrusion barrier packaging

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The raw material formulation of the polypropylene adhesive resin composition for multi-layer co-extruded barrier packaging (the following proportions are weight percent content) is as follows:

[0026] 69% random copolymer polypropylene

[0027] 15% functionalized modified random copolymerized polypropylene

[0028] 13% propylene-based elastomer

[0029] 3% Styrenic Block Copolymer

[0030] 0.08% thermal oxygen stabilizer

[0031] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polypropylene type adhesive resin for multilayer coextruded barrier packaging.

Embodiment 2

[0033] The raw material formulation of the polypropylene adhesive resin composition for multi-layer co-extruded barrier packaging (the following proportions are weight percent content) is as follows:

[0034] 65% random copolymer polypropylene

[0035] 18% functionalized modified random copolymer polypropylene

[0036] 15% propylene-based elastomer

[0037] 2% Styrenic Block Copolymer

[0038] 0.1% thermal oxygen stabilizer

[0039] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polypropylene type adhesive resin for multilayer coextruded barrier packaging.

Embodiment 3

[0041] The raw material formulation of the polypropylene adhesive resin composition for multi-layer co-extruded barrier packaging (the following proportions are weight percent content) is as follows:

[0042] 60% random copolymer polypropylene

[0043] 20% functionalized modified random copolymer polypropylene

[0044] 18% propylene-based elastomer

[0045] 2% Styrenic Block Copolymer

[0046] 0.12% thermal oxygen stabilizer

[0047] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polypropylene type adhesive resin for multilayer coextruded barrier packaging.

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Abstract

The invention discloses a preparation method of polypropylene type bonding resin for multi-layer coextrusion barrier packaging. The raw materials include (by weight percent) 50% to 80% of polypropylene random copolymer, 10% to 30% of functionalized modified atactic polypropylene, 10% to 30% of propylene based elastomer, 1% to 10% of styrene block copolymer and 0.01% to 1% of thermal oxygen stabilizer. The resin is obtained in extruded and granulated manners through a double screw extruder by the plasticating and blending process. The bonding resin is applied to the bonding layers of polypropylene (PP) / Niron (PA) or polypropylene (PP) / ethylene vinyl alcohol copolymer (EVOH) multi-layer coextrusion barrier packaging films (pieces), the processing performance is fine, the transparency is high, thermal resistance is fine, fisheye is few, the bonding performance is excellent, and a good bonding layer material is provided in the field of polypropylene type multi-layer coextrusion barrier packaging.

Description

technical field [0001] The invention belongs to the field of polymer functional materials, relates to the technical field of hot-melt adhesives, in particular to a method for preparing a polypropylene-type adhesive resin for multi-layer co-extruded barrier packaging, which is mainly used as polypropylene (PP) / nylon (PA) Or the adhesive layer of polypropylene (PP) / ethylene-vinyl alcohol copolymer (EVOH) multilayer co-extruded barrier packaging film (sheet). Background technique [0002] In recent years, the proportion of plastic packaging materials replacing traditional packaging materials has been growing rapidly, and high value-added functional plastic packaging materials represented by multi-layer co-extruded barrier functional films (sheets) are increasingly being received by the packaging industry and food favored by the industry. [0003] Multi-layer co-extrusion technology refers to directly using more than three kinds of plastic particles (or powder) as raw materials...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J123/14C09J11/08B32B37/12B29C47/92B29C48/92
Inventor 范德辉黄昌政吴雪生
Owner HEYUAN PLG MATERIALS
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