86results about How to "Less crystal point" patented technology

The invention provides a preparation method of extinction polyvinyl chloride resin. The preparation method comprises the following steps: acquiring vinyl chloride monomer, deionized water, an initiator, a buffering agent, a dispersant and a matting agent which serve as reaction raw materials; performing pre-emulsification treatment on the matting agent by use of part of the dispersant; adding the vinyl chloride monomer, the deionized water, the initiator, the buffering agent and the rest dispersant into a polymerization kettle, performing polyreaction, and adding the matting agent subjected to pre-emulsification treatment during the reaction process so as to prepare the extinction polyvinyl chloride resin, wherein the matting agent is a monomer or polymer containing two or more reaction active functional groups, the dosage of the deionized water accounts for 105-200% of the weight of the vinyl chloride monomer, the dosage of the initiator accounts of 0.04-0.18% of the weight of the vinyl chloride monomer, the total dosage of the dispersant accounts for 0.04-0.15% of the weight of the vinyl chloride monomer, the dosage of the buffering agent accounts for 0.06-0.18% of the weight of the vinyl chloride monomer, and the dosage of the matting agent accounts for 0.01-8.0% of the weight of the vinyl chloride monomer. The prepared extinction polyvinyl chloride resin is fewer in crystal spot and good in extinction effect.

The invention discloses a polyethylene type adhesive resin for multilayer co-extrusion barrier package. The polyethylene type adhesive resin comprises the following formula raw materials in percentage by weight: 40-80 percent of high density polyethylene (HDPE), 10-30 percent of functionalization modified high density polyethylene, 15-30 percent of vinyl elastomer, 1-10 percent of ethylene vinyl acetate copolymer (EVA), 0.01-1 percent of hot oxygen stabilizer. The polyethylene type adhesive resin is prepared by the following steps: performing a plasticizing and blending process by adopting a twin-screw extruder, extruding, and granulating, thereby obtaining the product. The adhesive resin disclosed by the invention is used for an adhesive layer of a polyethylene (PE)/nylon (PA) or polyethylene (PE)/ethylene-vinyl alcohol copolymer (EVOH) multilayer co-extrusion barrier package film (sheet) and is excellent in processability, high in transparency, high in heat resistance and fewer in grain points, is particularly excellent in adhesive performance, and a good adhesive layer material is provided for the field of polyethylene type multilayer co-extrusion barrier package.

The invention relates to the technical field of electrostatic film, and in particular, relates to a polyvinyl chloride electrostatic film and a preparation method thereof, wherein the polyvinyl chloride electrostatic film comprises the following raw materials in parts by weight: 80-120 parts of PVC resin, 46-73 parts of a plasticizer, 1-3 parts of a heat stabilizer, 3-7 parts of an anti-electrostatic agent, 0.3-0.7 part of a gelatinizing agent, 0.02-0.03 part of a pigment powder, and 0.1-0.3 part of other auxiliary agents. The polyvinyl chloride electrostatic film has high electrostatic resistance, has high anti-electrostatic effect and protection functions, has high self-adhesive performance, and has excellent stable performance under high temperature conditions; the polyvinyl chloride electrostatic film also has the advantages of being ultra thin, tough, transparent, self-adhesive, good in transparency, small in watermarks and the like, has fewer crystal points and low-temperature resistance, and has excellent comprehensive performance.

The invention discloses adhesive resin for a barrier composite hose and a preparation method and application thereof. The preparation method comprises the following steps of: firstly dissolving the following materials in parts by weight: 0.1-0.5 part of initiating agents, 1-3 parts of maleic anhydride and 0.5-1.5 parts of acrylamide into acetone, then uniformly mixing with 100 parts of PE, and carrying out reactive extrusion to obtain a maleic anhydride and acrylamide double-monomer grafted PE master batch; then carrying out blending extrusion on the following materials in parts by weight: 20-30 parts of the PE master batch, 50-70 parts of linear low density polyethylene, 10-20 parts of polyolefin elastomers, 0.05-0.15 part of fluoropolymer processing auxiliary agents and 0.2-0.5 part of antioxidants for granulation to obtain the adhesive resin for the barrier composite hose. The adhesive resin disclosed by the invention forms a transparent granule with a natural color in appearance, is stable in property and few in eutectic points and achieves the stripping strength on adhering to EVOH more than 250 N/cm. The barrier composite hose prepared by using the adhesive resin has the advantages of good adhesive property of various layers, high barrier property and smoothness of inner and outer surfaces.

The invention discloses a preparation method of an adhesive resin for a multilayer coextruded plastic composite hose. The adhesive resin comprises the following raw materials in percentage by weight: 30%-70% of linear low density polyethylene (LLDPE), 10%-30% of functionalized modified LLDPE, 10%-30% of vinyl elastomer, 5%-20% of low density polyethylene (LDPE) and 0.01%-1% of a thermal oxidation stabilizer. The adhesive resin is prepared by extruding and pelletizing in a twin-screw extruder through a plasticizing blending process. The adhesive resin disclosed by the invention is used for the adhesive layer of the multilayer coextruded plastic composite hose of polyethylene (PE)/ethylene-vinyl alcohol copolymer (EVOH), and is excellent in processability, good in heat resistance and few in crystal points, and in particular, excellent in adhesive property; as a result, a good adhesive layer material is provided for the multilayer coextruded plastic composite hoses.

The invention discloses a preparation method of polypropylene type bonding resin for multi-layer coextrusion barrier packaging. The raw materials include (by weight percent) 50% to 80% of polypropylene random copolymer, 10% to 30% of functionalized modified atactic polypropylene, 10% to 30% of propylene based elastomer, 1% to 10% of styrene block copolymer and 0.01% to 1% of thermal oxygen stabilizer. The resin is obtained in extruded and granulated manners through a double screw extruder by the plasticating and blending process. The bonding resin is applied to the bonding layers of polypropylene (PP) / Niron (PA) or polypropylene (PP) / ethylene vinyl alcohol copolymer (EVOH) multi-layer coextrusion barrier packaging films (pieces), the processing performance is fine, the transparency is high, thermal resistance is fine, fisheye is few, the bonding performance is excellent, and a good bonding layer material is provided in the field of polypropylene type multi-layer coextrusion barrier packaging.

The invention discloses bonding resin for an aluminum-plastic board and a preparation method thereof. The bonding resin is obtained by extrusion-granulation by a plasticizing blending process using atwin-screw extruder, and has high bonding strength, good bonding durability and film forming performance, less crystal points, and good heat and oxygen aging resistant performance, especially, by introducing HIPS, the bonding speed of the bonding resin is greatly improved, and simultaneously the bonding strength and durability are improved, so as to solve the defects of low bonding strength and poor stability caused by the untimely bonding reaction of the aluminum-plastic board in a high-speed production process, thereby greatly improving the production speed and bonding stability of the aluminum-plastic board.

The invention relates to a high-leakproofness multichannel packaging composite membrane and a production technology thereof. The composite membrane is formed by compounding a PET membrane, an aluminumfoil membrane and a three-layer co-extrusion PE membrane through an adhesive; the three-layer co-extrusion PE membrane comprises a corona layer, an intermediate layer and a heat-seal layer, wherein the corona layer comprises linear low-density polyethylene, low-density polyethylene and a fluorine-containing processing aid, the intermediate layer comprises low-density polyethylene, linear low-density polyethylene and high-density polyethylene, the heat-seal layer comprises first metallocene linear low-density polyethylene, second metallocene linear low-density polyethylene, polybutylene, a slipping agent and open masterbatches, and the melting index of the first metallocene linear low-density polyethylene is smaller than that of the second metallocene linear low-density polyethylene. The composite membrane has excellent thickness stability, the friction coefficient is 0.2-0.3, and machine running is facilitated; the heat-seal strength and heat-bonding strength are high, the membrane isresistant to negative pressure larger than or equal to 0.8 MPa, and the leakproofness is excellent; the Elmendorf tearing force is low, the thin membrane is easy to cut, and filament generation doesnot occur.

The invention discloses a low-temperature-resistant bidirectionally-stretched polypropylene thin film and a preparation method of the same. The polypropylene thin film comprises, from exterior to interior, a low-temperature-resistant anti-adhesion layer, a low-temperature-resistant core layer and a low-temperature-resistant corona treatment layer. The low-temperature-resistant core layer is composed of 30-70% of homo-polypropylene, 10-40% of a thermoplastic elastic master batch, and 20-50% of a low-temperature-resistant master batch. The low-temperature-resistant anti-adhesion layer and the low-temperature-resistant corona treatment layer are both composed of 50-70% of copolymerized modified polypropylene, 25-40% of a low-temperature-resistant master batch and 2-10% of a SiO2 anti-adhesion agent. The polypropylene thin film has excellent low-temperature-resistant performance, has excellent use performance even at -30 DEG C, is soft, is excellent in printing performance, has excellent physical performance and is simple in preparation method.

The present invention discloses a low-ash and high-density polyethylene resin and a preparation method thereof, wherein the weight average relative molecular mass of the low-ash and high-density polyethylene resin is 3.0*10<5>-9.0*10<5>, the relative molecular mass distribution is 5-9, the density is 0.940-0.965 g/cm<3>, and the ash content is less than 100 ppm. According to the present invention, the low-ash and high-density polyethylene resin has advantages of uniform composition, low ash, low metal impurity content, and the like; with the three-reaction kettle series connection method, the relative molecular mass, the relative molecular mass distribution and the co-polymerization monomer distribution of the polymerization product are easy to adjust, and the method can be directly used for molding of the wet lithium-ion battery separation membrane; and the molded microporous separation membrane has characteristics of uniform pore size distribution, less pinholes, less fisheye, high yield, high tensile strength, and high puncture strength.

The invention relates to a transparent TPU film with barrier performance and a preparation method of the transparent TPU film. The transparent TPU film comprises the following components in percentage by weight: 40-60% of thermoplastic polyurethane, 2-5% of SBS, 20-30% of K adhesive, 5-8% of inorganic filler and 12-20% of barrier agent. The preparation method comprises the following concrete steps of (1) after mixing all the materials, plasticizing TPU particles by using a single-screw extruder to form a semi-finished product; (2) directly connecting the single-screw extruder to a filtering machine of calendar equipment, and carrying out impurity filtration and re-plasticization on the semi-finished product on the filtering machine of the calendar equipment; and (3) processing the plasticized semi-finished product by using four-roller molding equipment to mold the film. The TPU film prepared by using the preparation method has high transparency and favorable barrier performance, tensile strength and processability.

The invention discloses a biaxially oriented polypropylene protecting film for a base material of a flexible printed circuit board and a preparation method of the biaxially oriented polypropylene protecting film. The biaxially oriented polypropylene protecting film is of a three-layer structure consisting of an inner surface layer, a middle layer and an outer surface layer, wherein the middle layer comprises an antistatic master batch, a flexible master batch and homo-polypropylene; the inner surface layer comprises an anti-sticking master batch, a flexible master batch, an antistatic master batch and homo-polypropylene; the outer surface layer comprises an anti-sticking master batch, a flexible master batch and homo-polypropylene; the flexible master batch comprises an ethylene-propylene polymer, an ethylene-butylene polymer, a propylene-butylene polymer, low-density polyethylene and linear low-density polyethylene. The biaxially oriented polypropylene protecting film has the advantages of good flexibility, excellent physical performance, optical performance and printing performance, good tear resistance, low static electricity, simple processing process and the like, and the base material can be maximally protected.

The invention discloses a grafting reaction device. The grafting reaction device comprises film casting equipment, grafting addition agent dispersion pre-reaction equipment and reactive extrusion grafting equipment, wherein the film casting equipment is used for extruding a premixed material in a mixed mode and casting the premixed material into a polymer film; the grafting addition agent dispersion pre-reaction equipment is used for dispersing grafting addition agents onto the polymer film and making the grafting addition agents have a pre-grafting reaction with the polymer film; the reactive extrusion grafting equipment is used for grafting functional monomers to a polymer molecule chain to form a graft polymer. According to the grafting reaction device, the polymer is cast to form the film, the grafting addition agents are dissolved in a dispersing agent and sprayed on the molten polymer film in a mist spray mode, the pre-grafting reaction happens to the surface of the molten polymer film, a grafting reaction is completely conducted in the reactive extrusion grafting equipment, a trace of the grafting addition agents are uniformly dispersed, the intercoupling probability of free radical active points of the polymer is lowered when the material is constantly sheared in a screw rod and an interface is updated so that the occurrence probability of crosslinking side reactions can be lowered, and the graft polymer which is high in grafting ratio, small in fisheye quantity and small in smell is obtained.

The invention provides a polypropylene film used for an ultra-thin type aluminum-plastic film. The polypropylene film comprises a polypropylene outer layer, a polypropylene core layer and a polypropylene heat-seal layer, wherein the polypropylene core layer is arranged between the polypropylene outer layer and the polypropylene heat-seal layer, and the polypropylene outer layer, the polypropylenecore layer and the polypropylene heat-seal layer are sequentially compounded together. The invention also provides a preparation method of the polypropylene film used for the ultra-thin type aluminum-plastic film. According to the preparation method, polypropylene resin of different melting points are combined, so that polypropylene has better temperature resistance; and a charging device with a vacuumizing or nitrogen sealing function and a secondary filtration technology are used, and one or more combinations of other raw materials is added, so that the produced casting polypropylene film has fewer crystal points. The casting polypropylene film is applicable to the ultra-thin type aluminum-plastic film, thinning is guaranteed, and packaging and depth scouring performances are also guaranteed at the same time.

The invention discloses a manufacturing process of a biaxially stretched color base film for manufacture process protection of electronic products, and belongs to the field of manufacturing color basefilm. The manufacturing process comprises the steps of manufacture of a color masterbatch and manufacture and production of a color film by using a five-layer biaxial stretching device, specificallythe color masterbatch is produced by using a tandem type screw extruder; and the production of the color film by using the five-layer biaxial stretching device includes the following steps: drying, extruding, casting, longitudinal stretching, transverse stretching, heat treatment and winding, specifically the step of extruding includes extruding by a main extruder and extruding by using four auxiliary extruders. the four auxiliary extruders used in the step of extruding by using the four auxiliary extruders are able to make the film surface color be uniformly distributed, less in crystal point, less in bubbles, and high in gloss; the corona surface has a uniform corona value and no corona on the back surface, and the non-corona surface has no glue; the pollutant to a main batching system of a production line is less; and products are converted quickly after production is completed.

The invention relates to the technical field of wrapping films, and discloses a metallocene linear low-density polyethylene reinforced wrapping film manufacturing process. The process is characterizedin that mLLDPE-a and mLLDPE-b in a wrapping film structure are two metallocene linear low-density polyethylene with different melt indexes respectively, are used for improving the strength, and are used for adjusting melt index of blended material according to different equipment characteristics; an mLLDPE-c is metallocene linear low density polyethylene with a high viscosity mark and is used forimproving the viscosity of a finished product film, polyethylene is thermoplastic resin prepared by polymerizing ethylene and also comprises a copolymer of ethylene and a small amount of alpha-olefinin industry, and the polyethylene is odorless, nontoxic and wax-like in hand feeling, has excellent low-temperature resistance (the lowest use temperature can reach minus 100 DEG C to minus 70 DEG C)and good chemical stability, can resist erosion of most acids and alkalis (does not resist acids with oxidizing properties), is insolubility in common solvents at normal temperature, and has low water absorption and excellent electrical insulation, and the layer A is the mLLDPE-a + mLLDPE-b + LLDPE; the B layer is mLLDPE-a + mLLDPE-b + LLDPE, the C layer is mLLDPE-a + mLLDPE-b + LLDPE, the D layer is mLLDPE-a + mLLDPE-b + LLDPE, and the E layer is mLLDPE-c.

The invention provides adhering resin for a high-barrier bottle and a preparation method thereof. The adhering resin is prepared from the following components of 15 to 30 parts of maleic anhydride-grafted linear low density polyethlyene master batch, 15 to 30 parts of high density polyethlyene, 15 to 30 parts of low density polyethlyene, 20 to 30 parts of POE (polyolefin elastomer), 5 to 10 partsof polylactic acid, 0.2 to 1 part of talcum powder, 0.2 to 0.5 part of antioxidant, 1 to 10 parts of plasticizer, and 2 to 6 parts of silane coupling agent. The invention further provides a preparation method of the adhering resin for the high-barrier bottle. The adhering resin for the high-barrier bottle and the preparation method have the advantages that the self color is transparent, the property is stable, and the number of crystal points is fewer; the adhering property of each layer of the prepared high-barrier property is high, the barrier property is strong, the inner surface and outersurface are smooth, the heat stability is good, and the like.

The invention relates to a high temperature-resistant nanosized self-adhesive optical protective film and a production method thereof. The self-adhesive optical protective film comprises a self-adhesive layer, an intermediate layer and an unwinding layer, wherein the self-adhesive layer comprises metallocene polyethylene elastomer resin, soft rubber resin and ternary polymerized polypropylene resin at a mass ratio of (70-80):(10-20):(5-15), the intermediate layer includes high-density polyethylene resin, linear low-density polyethylene resin and low-density polyethylene resin at a mass ratio of (25-35):(35-45):(25-40), and the unwinding layer includes block polypropylene resin and a fluorine-containing auxiliary agent at a mass ratio of (90-98):(2-10). The self-adhesive optical protectivefilm is produced in a multi-layer coextrusion tape-casting mode, and has the excellent properties of high temperature resistance, no shrinkage, repeated sticking and no precipitation.

The invention discloses a hot melt adhesive for a high-performance polypropylene barrier film as well as a preparation method and application of the hot melt adhesive. The hot melt adhesive is prepared from 10 to 30 parts of maleic anhydride grafted polypropylene, 35 to 60 parts of polypropylene-random-copolymer, 0 to 20 parts of low-density polyethylene, 10 to 30 parts of metallocene polyolefin plastomer, 0 to 5 parts of PP grafted maleic anhydride wax and 0.1 to 0.5 part of antioxidant. Through component optimization, the hot melt adhesive has the characteristics of excellent bonding performance, no pungent smell and few crystal points, and solves the problems of poor bonding force, strong smell and many crystal points of the hot melt adhesive for the domestic polypropylene barrier film.

The invention relates to a polyethylene composition for a greenhouse film. The polyethylene composition is prepared from the following raw materials in parts by weight: 100 parts of mLLDPE resin, 0.03to 0.05 parts of peroxide, 6 to 14 parts of maleic anhydride master batch, 0.1 to 0.5 part of antioxidant, 0.04 to 0.07 part of rheological agent, 1 to 1.5 parts of heat preserving additives, and 0.05 to 0.10 part of lubricating agents. The composition has higher melt viscosity, and the prepared greenhouse film has thermal insulation properties.

The invention provides a special PET food packaging sheet extrusion production line, which sequentially comprises a material feeding unit, a molding unit, a cooling trimming unit and a finished product collection unit from right to left, wherein the material feeding unit comprises a vacuum feeder, a material tank, a dryer and a material hopper, the molding unit comprises a rack, a support arm, a cylinder, a screen changer, a metering pump, a distributor, a mold, a three-roller calender and a double-working position laminating device, the cooling trimming unit comprises a cooling bracket, a round cutter device and a corona machine, the finished product collection unit comprises a drawing machine and a winding machine, the cylinder and the support arm are sequentially arranged on the rack, and the screen changer, the metering pump and the mold are sequentially arranged on the support arm. According to the present invention, the produced special PET food packaging sheet has characteristics of less crystal point, no whitening during plastic suction, neat winding and high comprehensive energy efficiency; and the production line can further be used for producing PS, PP, PE and other sheet materials.