The present invention discloses a 
lithium ion battery composite separation membrane and a preparation method thereof, and belongs to the technical field of 
lithium ion batteries, wherein at least a surface of a 
polyolefin separation membrane is coated with a modified 
natural rubber polymer coating. According to the invention, the 
polyolefin separation membrane and the modified 
natural rubber are combined to form the composite separation membrane, such that mechanical properties of the 
natural rubber can be improved, and the original pore closing characteristic of the 
polyolefin separation membrane can be maintained and utilized so as to improve safety of the battery, enhance bonding force between the separation membrane and the positive 
electrode and bonding force between the separation membrane and the negative 
electrode, eliminate the interface effect, and improve cycle stability of the battery; and the 
inorganic nanoparticles are added to the modified 
natural rubber latex, such that the 
crystallinity of the 
polymer can be reduced to a certain extent, the 
mechanical strength of the separation membrane and the carrier concentration can be increased, the interface compatibility between the separation membrane and the 
lithium electrode can be effectively improved, and the interface is stable.