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479results about How to "Have mechanical strength" patented technology

Composite material based on nanometer, preparation method of composite material and application in flexible energy storage device

The invention relates to the field of chemical energy storage devices such as super capacitors, batteries and the like, and particularly discloses a composite material based on nanometer, a preparation method of the composite material and application in a flexible energy storage device, which solve the problem that common energy storage devices are difficult to be bent and deform. Nanometer active materials are compounded with flexible fibers, high-energy-storage characteristics of the nanometer active materials and excellent flexibility of flexible fiber materials are integrated, the quality percentage of the nanometer active materials ranges from 0.1% to 40%, the rest components of the composite material are the flexible fibers, the flexible nanometer composite material in a three-dimensional communication network structure is formed, furthermore, the composite material can be used as an electrode active material and a current collector simultaneously so as to be assembled to form the bendable flexible energy storage device, higher specific capacity can be realized under a bending condition and is equivalent to that when the flexible energy storage device is not bent, and the composite material can be expected to be applied to the field of flexible devices in the future.
Owner:INST OF METAL RESEARCH - CHINESE ACAD OF SCI

Electrolyte film and porous substrate and preparation thereof, lithium ion secondary battery

The invention relates to a gel-type polymer electrolyte film for a lithium ion secondary battery and a process for preparation, and a lithium ion secondary battery which contains the electrolyte film. The gel-type polymer electrolyte film for the lithium ion secondary battery can be obtained through the following method: preparing polyvinylidene fluoride nonwoven through the electrostatic spinning method, making the surface of the polyvinylidene fluoride nonwoven activate through radiating electron beams for the obtained the polyvinylidene fluoride nonwoven in air, contacting a methyl methacrylate monomer and the polyvinylidene fluoride nonwoven after the surface activation, thereby obtaining the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate. Furthermore, the lithium ion battery electrolyte film can be obtained through making the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate absorbs a certain amount of electrolytic solution. The invention develops the respective advantages in the lithium ion battery owing to using the polyvinylidene fluoride nonwoven whose surface is grafted with polymethyl methacryate, compared with singly using polyvinylidene fluoride or polymethyl methacryate or the both simple composite, and eliminates the disadvantages caused by singly using one material or several materials. The electrolyte film has high ion electrical conductivity under ambient temperature after absorbing the electrolytic solution, and can manifest excellent heavy-current discharge performance and circulation stability after being assembled in the batteries.
Owner:PANASONIC CORP +1

Preparation method of graphene-carbon nanotube-nano tin dioxide three-dimensional composite material and product thereof

The invention discloses a preparation method of a graphene-carbon nanotube-nano tin dioxide three-dimensional composite material, which comprises the following steps: (a) by using deionized water as a solvent, sequentially adding graphene oxide, stannous dichloride and multiwall carbon nanotubes as solutes, and mixing; (b) performing ultrasonic reaction on the mixed solution at 25-40 DEG C under the ultrasonic power of 100-300W for 1-2 hours; and (c) transferring the solution subjected to ultrasonic reaction into a hydrothermal kettle, performing hydrothermal treatment at 120-300 DEG C for 6-72 hours, and slowly cooling to room temperature, thereby obtaining the three-dimensional-structure graphene-carbon nanotube-nano tin dioxide composite material product. The invention also discloses a corresponding product and application thereof. The method disclosed by the invention can be used for preparing the three-dimensional-structure graphene composite material in an economic environment-friendly and convenient-operation mode; and the graphene-carbon nanotube-nano tin dioxide three-dimensional composite material has the characteristics of high specific surface area, porousness, light weight, long cycle life and the like.
Owner:HUAZHONG UNIV OF SCI & TECH

Graphene array-loaded lithium titanate/carbon nanotube composite array electrode and preparation method and application thereof

The invention discloses a graphene array-loaded lithium titanate / carbon nanotube composite array electrode and a preparation method and application thereof. The preparation method comprises the following steps of utilizing a microwave plasma enhanced chemical vapor phase deposition technique to vertically grow a graphene array on a carbon cloth; utilizing an atom layer deposition technique to grow TiO2 (titanium dioxide) on the obtained graphene array; dissolving lithium hydroxide into water to form a solution A; putting the vertical graphene-loaded TiO2 composite electrode material into the solution A, performing hydrothermal reaction, washing, drying and calcining; utilizing a chemical vapor phase deposition technique, using acetylene as a carbon source, and growing a carbon nanotube on the graphene array-loaded lithium titanate composite array electrode under the hydrogen and argon atmospheres, so as to obtain the graphene array-loaded lithium titanate / carbon nanotube composite array electrode. When the graphene array-loaded lithium titanate / carbon nanotube composite array electrode is used as the negative electrode material of lithium ion batteries, the high-rate property and circulating stability are excellent.
Owner:ZHEJIANG UNIV

Slowly-released filter stick essence microcapsule and preparation method thereof

The invention discloses a slowly-released filter stick essence microcapsule and a preparation method thereof. The slowly-released filter stick essence microcapsule is prepared from the following raw materials in parts by weight: 12-18 parts of sodium alginate, 6-12 parts of Arabic gum, 15-25 parts of emulsifier and 10-15 parts of filter stick essence. The preparation method comprises the following steps: firstly, respectively preparing an Arabic gum solution and a sodium alginate solution; then, injecting the sodium alginate solution into the Arabic gum solution proportionally to obtain a mixed wall material solution; in the stirring process, successively adding the emulsifier and the filter stick essence to obtain emulsion; standing; and carrying out high-voltage electrostatic treatment after foam is eliminated to obtain the microcapsule. The slowly-released filter stick essence microcapsule prepared by the invention has the advantages that the embedding rate is more than 80%, the particle diameter uniformity is good, the essence retention rate is more than 85% after the microcapsule is stored for 6 months at 20 DEG C, and the release rate of the essence microcapsule at 40 DEG C is about 6 times of the release rate of the essence microcapsule at 20 DEG C.
Owner:UNIV OF SHANGHAI FOR SCI & TECH

Lithium silicon alloy material with surface modification layer, preparation method thereof, electrode and electrochemical energy storage device and negative electrode lithium-supplementing method

The invention discloses a lithium silicon alloy material with a surface modification layer, a preparation method thereof, an electrode and an electrochemical energy storage device and a negative electrode lithium-supplementing method. The lithium-silicon alloy material is in the form of particles, the particle size of the particles is 0.1 to 50 micrometers, and the lithium-silicon alloy material comprises lithium-silicon alloy particles and a surface modification layer which covers the exposed surfaces of the lithium-silicon alloy particles. The outer layer of the surface modification layer isused for preventing the lithium-silicon alloy from coming into contact with the external environment, so that the lithium-silicon alloy can be stably stored and used in the dry air, and the reactionbetween the material and the electrolyte during the electrochemical cycle can be effectively prevented, and the cycle stability is improved; in addition, the lithium silicon alloy with the surface modification layer can be used as the negative electrode alone, the first efficiency of the battery can be improved, and can also be used as an additive in other negative electrodes without lithium element to supplement lithium and reduce the loss of effective lithium, and a lithium ion battery with high energy density is prepared.
Owner:CHINA ENERGY LITHIUM

A functional separator for a lithium-sulfur battery, a preparation method thereof and an application thereof in lithium-sulfur battery

The invention relates to a functional separator for a lithium sulfur battery, and a preparation method and application thereof, belonging to the technical field of electrochemistry. The functional separator of the invention is composed of a polymer separator matrix and a functional modification layer applied one side surface of the polymer separator matrix, wherein the functional modification layer comprises a binder, a conductive carbon material and a dendritic branched macromolecule. The adhesive of the invention has good adhesion and high stability. The conductive carbon material has a veryhigh electron conduction rate, can improve the utilization rate of the active substance and greatly reduce the internal impedance of the battery. The dendritic branch macromolecule contains more organic functional groups, the dendritic branched macromolecule has chemisorption to the polysulfide generated in the sulfur positive electrode region during the cycle, and the carbon material has physical adsorption to the dissolve polysulfide, thereby effectively inhibiting the shuttle effect in the lithium-sulfur battery. Therefore, the lithium sulfur battery prepared using the functional separatordescribed in the present invention exhibits excellent cycle performance and rate performance.
Owner:WUHAN UNIV

Preparation process of fuel cell electrode porous diffusion layer material carbon fiber paper

The invention relates to the field of fuel cell electrode porous diffusion layer materials, in particular to a preparation process of basic material carbon fiber paper for manufacturing fuel cell electrode porous diffusion layers. The carbon fiber paper can be produced on common paper machine production lines in a batch mode and meets the requirement for manufacture of fuel cell electrode porous diffusion layer electrodes. The preparation process comprises the steps of (1) performing surface treatment to short carbon fiber; (2) performing surface treatment to conductive carbon black; (3) smashing raw wood pulp and placing the raw wood pulp into a pulping pond, wherein the ratio of the raw wood pulp to water is 5-15%; and the like. The carbon fiber paper produced by means of the preparation process can meet the requirement for manufacture of the fuel cell electrode porous diffusion materials, can evenly support catalyst layers in electrodes and stabilizing electrode structures, further has functions of providing gas channels, electronic channels and drainage channels for electrode reaction and the like, and has porous structures, excellent gas generating performance, high conductivity, certain mechanical strength, chemical stability and heat stability.
Owner:SHENYANG HUATIANXIN CARBON FIBER ELECTRIC HEATINGPROD
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