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Method for preparing polyethylene type adhesive resin for multilayer co-extrusion barrier package

A multi-layer co-extrusion and bonding resin technology, which is applied in packaging, wrapping paper, transportation and packaging, etc., can solve the problem of excessive tensile stress and strain of bonding strength, affecting product quality and production efficiency, and delamination at edges and corners and other problems, to achieve excellent bonding performance, improve product quality and production efficiency, and achieve lasting and stable bonding strength

Active Publication Date: 2015-03-25
HEYUAN PLG MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When the bonding strength is not enough, the co-extruded film will delaminate during the production of multi-layer co-extruded film or when stretched and packaged by vacuum, which seriously affects product quality and production efficiency
At present, when using polypropylene multi-layer co-extruded film or polyethylene multi-layer co-extruded film to package angular products (such as trotters, beef steaks, and electronic printed circuit boards, etc.), the angularity of the corners will be reduced during the vacuum stretching process. Delamination often occurs at the edge, indicating that the bonding strength of the adhesive resin at the edge of the edge is severely reduced or lost due to the relative excessive tensile stress and strain between the layers during vacuum stretching. Therefore, in the prior art The use of polypropylene-type bonding resins and polyethylene-type bonding resins imposes higher requirements

Method used

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  • Method for preparing polyethylene type adhesive resin for multilayer co-extrusion barrier package
  • Method for preparing polyethylene type adhesive resin for multilayer co-extrusion barrier package
  • Method for preparing polyethylene type adhesive resin for multilayer co-extrusion barrier package

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] The raw material formula (the following proportions are weight percentages) of the polyethylene adhesive resin composition for multilayer co-extruded barrier packaging is as follows:

[0026] 63% HDPE

[0027] 15% functionalized modified high density polyethylene

[0028] 20% ethylene-butylene copolymer elastomer

[0029] 2% ethylene-vinyl acetate copolymer

[0030] 0.08% thermal oxygen stabilizer

[0031] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polyethylene type adhesive resin for multilayer coextruded barrier packaging.

Embodiment 2

[0033] The raw material formula (the following proportions are weight percentages) of the polyethylene adhesive resin composition for multilayer co-extruded barrier packaging is as follows:

[0034] 54.5% HDPE

[0035] 18% functionalized modified high density polyethylene

[0036] 25% ethylene-octene copolymer elastomer

[0037] 2.5% ethylene-vinyl acetate copolymer

[0038] 0.1% thermal oxygen stabilizer

[0039] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polyethylene type adhesive resin for multilayer coextruded barrier packaging.

Embodiment 3

[0041] The raw material formulation (the following proportions are weight percentages) of the polyethylene adhesive resin composition for multilayer co-extruded barrier packaging is as follows:

[0042] 50% HDPE

[0043] 20% functionalized modified high density polyethylene

[0044] 27% ethylene-butylene copolymer elastomer

[0045] 3% ethylene-vinyl acetate copolymer

[0046] 0.12% thermal oxygen stabilizer

[0047] The above-mentioned components are extruded and granulated by plasticizing and blending with a twin-screw extruder. The length-to-diameter ratio of the extruder is L / D=40:1, and the processing temperature is 150-230°C. Polyethylene type adhesive resin for multilayer coextruded barrier packaging.

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Abstract

The invention discloses a polyethylene type adhesive resin for multilayer co-extrusion barrier package. The polyethylene type adhesive resin comprises the following formula raw materials in percentage by weight: 40-80 percent of high density polyethylene (HDPE), 10-30 percent of functionalization modified high density polyethylene, 15-30 percent of vinyl elastomer, 1-10 percent of ethylene vinyl acetate copolymer (EVA), 0.01-1 percent of hot oxygen stabilizer. The polyethylene type adhesive resin is prepared by the following steps: performing a plasticizing and blending process by adopting a twin-screw extruder, extruding, and granulating, thereby obtaining the product. The adhesive resin disclosed by the invention is used for an adhesive layer of a polyethylene (PE) / nylon (PA) or polyethylene (PE) / ethylene-vinyl alcohol copolymer (EVOH) multilayer co-extrusion barrier package film (sheet) and is excellent in processability, high in transparency, high in heat resistance and fewer in grain points, is particularly excellent in adhesive performance, and a good adhesive layer material is provided for the field of polyethylene type multilayer co-extrusion barrier package.

Description

technical field [0001] The invention belongs to the field of polymer functional materials, relates to the technical field of hot-melt adhesives, in particular to a preparation method of polyethylene-type adhesive resin for multi-layer co-extruded barrier packaging, which is mainly used as polyethylene (PE) / nylon (PA) Or the adhesive layer of polyethylene (PE) / ethylene-vinyl alcohol copolymer (EVOH) multilayer co-extruded barrier packaging film (sheet). Background technique [0002] In recent years, the proportion of plastic packaging materials replacing traditional packaging materials has been growing rapidly, and high value-added functional plastic packaging materials represented by multi-layer co-extruded barrier functional films (sheets) are increasingly being received by the packaging industry and food favored by the industry. [0003] Multi-layer co-extrusion technology refers to directly using more than three kinds of plastic particles (or powder) as raw materials, an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J123/08C09J151/06C09J11/06B32B7/12B65D65/40
Inventor 范德辉黄昌政吴雪生
Owner HEYUAN PLG MATERIALS
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