Nematic cholesteric phase multistable liquid crystal composition and liquid crystal display
A liquid crystal composition and liquid crystal display technology, which are applied in the directions of liquid crystal materials, instruments, chemical instruments and methods, can solve the problem of insufficient contrast of CLC display devices, and achieve the stability of small wavelengths with temperature changes, high contrast, and wide operating temperature. wide effect
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[0061] (1) Preparation of compounds represented by general formula I-a:
[0062] 1) The synthesis route of the intermediate M1-a of the compound represented by the general formula I-a:
[0063]
[0064] 2) Synthetic route for the preparation of compounds represented by general formula I-a:
[0065]
[0066] Wherein, n is an integer of 2-9.
[0067] (2) Preparation of compounds represented by general formula I-b:
[0068] 1) The synthetic route of the intermediate M1-b of the compound represented by the general formula I-b:
[0069]
[0070] 2) Synthetic route for the preparation of compounds represented by general formula I-b:
[0071]
[0072] Wherein, n is an integer of 2-9.
[0073] Compound I-1 to Compound I-5 were prepared using the above synthesis process and route, wherein the chirality of the final product comes from the raw material binaphthol (S- or R-), in other words, the above four compounds correspond to 8 compounds with Compounds with different ...
Embodiment 1
[0102] Embodiment 1: cholesteric mixed liquid crystal, wherein the total mass content of the nematic phase part is 97.56%, and the mass content of the chiral dopant is 2.44%. In the nematic phase part, terphenylacetylene isothiocyanate, biphenylacetylene isothiocyanate and terphenylacetylene isothiocyanate monomers are used to increase the birefringence of the mixed liquid crystal on the one hand, and increase its reflectivity to thereby Improve the contrast; on the other hand, increase its dielectric anisotropy to reduce the driving voltage of the formulation. The specific composition and properties of Embodiment 1 are shown in Table 3.
[0103] Table 3. Composition and properties of the cholesteric multistable liquid crystal composition of Example 1
[0104]
[0105]
Embodiment 2
[0113] Embodiment 2: cholesteric mixed liquid crystal, wherein the total mass content of the nematic phase part is 97.73%, and a chiral dopant of pentanephthalene is used, and its mass content is 2.27%. In the nematic phase part, the bicyclic pyridine isothiocyanate monomer is used together with the bicyclic pyridyl cyano monomer, which can also improve the contrast and reduce the driving voltage. The specific composition and performance of Embodiment 2 are shown in Table 5.
[0114] Table 5. Composition and properties of the cholesteric multistable liquid crystal composition of Example 2
[0115]
[0116]
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