A kind of modified urea-formaldehyde resin adhesive and preparation method thereof
A technology of urea-formaldehyde resin and adhesive, applied in the direction of adhesives, aldehyde/ketone condensation polymer adhesives, adhesive types, etc., can solve the problems of poor water resistance, reduced bonding strength, and increased product cost, and achieve low formaldehyde release The effect of increasing the amount, increasing the cross-linking density, and increasing the degree of branching
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Embodiment 1
[0022] A modified urea-formaldehyde resin adhesive, the raw material formula is shown in the following table 1:
[0023] Table 1 The molar ratio of formaldehyde to urea is 1.07:1 Raw material ratio of urea-formaldehyde resin:
[0024]
[0025] A kind of preparation method of above-mentioned modified urea-formaldehyde resin adhesive, is 1.07 to prepare raw materials by formaldehyde and urea molar ratio, and reaction step comprises:
[0026] 1) Put 591.2 parts by weight of 37% industrial formaldehyde into the reactor, add 208.3 parts by weight of the first batch of urea, adjust the pH value to 6.0, keep it at 60°C for 20 minutes, raise the temperature to 90°C within 20 minutes, and keep the pH at 5.5 -6.0, heat up to 90°C, add 30 parts by weight of polyvinyl alcohol solution after keeping warm for 20 minutes, keep warm for 20 minutes;
[0027] 2) Control the pH value to 7-9, add 5 parts by weight of reaction enhancer in batches, control the temperature at 85-90 ° C until the...
Embodiment 2
[0043] A modified urea-formaldehyde resin adhesive, the raw material formula is shown in the following table 3:
[0044] Table 3 The molar ratio of formaldehyde to urea is 1:0.98 Raw material ratio of urea-formaldehyde resin:
[0045]
[0046] A kind of preparation method of above-mentioned modified urea-formaldehyde resin adhesive, is that 1:0.98 is prepared raw material by formaldehyde and urea molar ratio, and reaction step comprises:
[0047] 1) Put 569.8 parts by weight of 37% industrial formaldehyde into the reactor, add 210.8 parts by weight of the first batch of urea, adjust the pH value to 6.0, keep it at 60°C for 20 minutes, raise the temperature to 90°C within 20 minutes, and keep the pH at 5.5 -6.0, heat up to 90°C, add 50 parts by weight of polyvinyl alcohol solution after keeping warm for 20 minutes, keep warm for 20 minutes;
[0048] 2) Control the pH value to 7-9, add 8 parts by weight of reaction enhancer dropwise, control the temperature at 85-90 ° C unti...
experiment example
[0064] Add 0.6% ammonium chloride and 0.4% citric acid to the urea-formaldehyde resins of the above examples and comparative examples respectively, and then add 32% flour to make three-layer plywood of 400×400mm.
[0065] Poplar veneer: dry to 10-14% moisture content; thickness 1.5mm;
[0066] The veneer adhesive used the product of Example 1-2 of the present invention and the product of Comparative Example 1-2.
[0067] Plywood is prepared according to the normal process as follows:
[0068] Glue sizing: double-sided sizing of the core board, the amount of glue applied is 300-320g / m 2 ;
[0069] Aging method and time: closed aging, 20-30 minutes;
[0070] Pre-compression pressure and time: pre-compression 40 minutes, pressure 0.9MPa;
[0071] Hot pressing pressure: 1.0MPa, hot pressing temperature is 110-120°C, hot pressing time is 60s / mm.
[0072] According to the test method of GB / T17657-1999 "Physical and Chemical Properties of Wood-Based Panels and Decorated Wood-bas...
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