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Thermoplastic resin composition having excellent reflectivity

A thermoplastic resin and composition technology, applied in the field of polyester thermoplastic resin composition and molded products formed therefrom, can solve the problems of insufficient mechanical properties, poor moldability and molding stability, low crystallization rate, etc.

Active Publication Date: 2016-01-06
LOTTE ADVANCED MATERIALS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, such polyester resin compositions also suffer from low crystallization rate, poor formability and molding stability, and insufficient mechanical properties

Method used

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  • Thermoplastic resin composition having excellent reflectivity
  • Thermoplastic resin composition having excellent reflectivity
  • Thermoplastic resin composition having excellent reflectivity

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0108] As listed in Table 1, 100 parts by weight of base resin containing 75 wt% of (A) polyester resin and 25 wt% of (B) white pigment, 3 parts by weight of (C1) core-shell structure impact modified A curing agent, and 0.2 parts by weight of (D) modified polyolefin resin were dry blended to prepare a thermoplastic resin composition. Subsequently, the thermoplastic resin composition was extruded at a nozzle temperature of 250° C. to 350° C. using a twin-screw extruder (φ=45 mm) to prepare pellets. The prepared pellets were dried at 100° C. for 4 hours or more, and then subjected to injection molding to prepare samples. The prepared samples were evaluated for reflectance, reflectance difference, and flexural strength by the following methods. The results are shown in Table 2.

Embodiment 2

[0110] As listed in Table 1, 100 parts by weight of base resin, 3 parts by weight of ( C1) A core-shell structure impact modifier, and 0.2 parts by weight of (D) modified polyolefin resin were dry blended to prepare a thermoplastic resin composition. Subsequently, the thermoplastic resin composition was extruded at a nozzle temperature of 250° C. to 350° C. using a twin-screw extruder (φ=45 mm) to prepare pellets. The prepared pellets were dried at 100° C. for 4 hours or more, and then subjected to injection molding to prepare samples. The prepared samples were evaluated for reflectance, reflectance difference, and flexural strength by the following methods. The results are shown in Table 2.

Embodiment 3

[0112] As listed in Table 1, 100 parts by weight of base resin, 3 parts by weight of ( C1) A core-shell structure impact modifier, and 0.5 parts by weight of (D) modified polyolefin resin are dry blended to prepare a thermoplastic resin composition. Subsequently, the thermoplastic resin composition was extruded at a nozzle temperature of 250° C. to 350° C. using a twin-screw extruder (φ=45 mm) to prepare pellets. The prepared pellets were dried at 100° C. for 4 hours or more, and then subjected to injection molding to prepare samples. The prepared samples were evaluated for reflectance, reflectance difference, and flexural strength by the following methods. The results are shown in Table 2.

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Abstract

A thermoplastic resin composition includes: a polyester resin; a white pigment; a core-shell structured impact modifier; and a modified polyolefin resin. The thermoplastic resin composition and a molded article formed from the same can exhibit excellent properties in terms of reflectance, reflectance maintenance at high temperature, and / or flexural strength.

Description

technical field [0001] The present invention relates to thermoplastic resin compositions. More particularly, the present invention relates to a polyester thermoplastic resin composition having excellent properties in reflectance, reflectance maintenance at high temperature, and flexural strength, and a molded article formed therefrom. Background technique [0002] Due to their remarkable energy efficiency and their long lifetime, light emitting diodes (LEDs) and organic light emitting diodes (OLEDs) are rapidly replacing existing light sources and are becoming the focus of attention. Typically LEDs form LED packages together with components such as reflectors, reflector cups, scramblers, and housings to maximize optical efficiency through high reflectivity. Such components need to withstand high temperatures while minimizing degradation in reflectivity and whiteness due to yellowing. [0003] Polyester resins, copolymers thereof, and blends thereof exhibit useful propertie...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L51/04C08L23/08C08K3/22C08K3/30C08K3/26C08K7/14
CPCH01L2224/48091C08L67/02H01L33/56C08K7/14C08L23/0869C08L51/06C08L51/085C08K3/013C08L2203/20H01L2924/00012H01L33/60
Inventor 姜兑坤朴赞武郑有珍金阳日金泰水洪尚铉
Owner LOTTE ADVANCED MATERIALS CO LTD