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A Zn in-situ and ex-situ coupling detoxification method in heavily polluted sites

A heavy pollution, site technology, applied in the restoration of polluted soil, chemical instruments and methods, fertilizer mixture, etc., can solve the problems of secondary pollution, high cost, large energy consumption, etc., achieve strong natural tolerance, reduce Cost, effect of Zn stabilization

Active Publication Date: 2020-12-15
山东环保产业集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The high temperature melting method is costly and consumes a lot of energy
The biological method has a long reaction cycle and is likely to cause secondary pollution by foreign biological agents
The effect of the curing method is unstable, and the curing agent is likely to cause secondary pollution to the soil
Patent No. 201510056406.6 introduces a solidification method for soil containing heavy metals, but this method uses a large amount of materials, and the cost is high. On the other hand, the solidification effect is unstable. For example, the added calcium oxide is prone to carbonation under natural conditions. Reduces the effect of alkaline curing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] (1) Mix sodium sulfate, sludge or carbon source solution according to a certain ratio, so that the dry sludge content of the mixed solution is 0.1-5%, the solid content is 0.5-5%, the organic carbon content is 0.5-5%, and the SO4 / The mass ratio of organic carbon is 0.7: 1, and the mixed solution is reacted for 2 days to obtain Zn soil remediation agent;

[0019] (2) Excavate 10m of Zn-containing site surface soil, then lay a mesh geomembrane on the bottom of the excavated site, and lay anti-seepage materials around the excavated site to build a semi-closed storage yard;

[0020] (3) The soil in step (2) is crushed to below 5 mm, then mixed with the medicament described in step (1), the mixing ratio is that the mass ratio of Zn-containing soil to medicament is 1:0.5, and then placed in step (2) Closed storage in the semi-enclosed yard;

[0021] (4) During the stockpiling period, keep the soil moisture content in the range of 5-60% in the initial 20 days, so that the bi...

Embodiment 2

[0023] (1) Mix sodium sulfate, sludge or carbon source solution according to a certain ratio, so that the dry sludge content of the mixed solution is 5-15%, the solid content is 5-15%, the organic carbon content is 5-15%, and the SO4 / The mass ratio of organic carbon is 0.5: 1, and the mixed solution is reacted for 1 day to obtain Zn soil remediation agent;

[0024] (2) Excavate 5m of Zn-containing site surface soil, then lay a mesh geomembrane on the bottom of the excavated site, and lay anti-seepage materials around the excavated site to build a semi-closed storage yard;

[0025] (3) The soil in step (2) is crushed to below 5 mm, then mixed with the medicament described in step (1), the mixing ratio is that the mass ratio of Zn-containing soil to medicament is 1:0.5, and then placed in step (2) Closed storage in the semi-enclosed yard;

[0026] (4) During the stockpiling period, keep the soil moisture content in the range of 5-60% in the initial 20 days, so that the biochem...

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PUM

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Abstract

The present invention adopts a Zn in-situ and ex-situ coupling detoxification method for heavily polluted sites. Sludge, carbon sources and sulfates are formulated into medicaments and applied to Zn-containing soils, and then special construction and maintenance methods are adopted to reduce ecological bacteria. The agent gradually penetrates into the ground and restores Zn in the deep contaminated soil. This method can remediate Zn-containing sites with high pollution depth at low cost and high efficiency, and at the same time treat waste with waste, and treat sludge.

Description

technical field [0001] The invention provides a new method for treating Zn-contaminated soil. Sludge, carbon source and sulfate are formulated into medicaments and applied to Zn-containing soil, and then a special maintenance method is adopted to efficiently fix Zn while avoiding sulfate. Secondary pollution, which belongs to the field of environmental protection. Background technique [0002] A large amount of soil is polluted by Zn due to the random discharge of mining and metallurgical wastewater. Current methods for treating zinc-containing soils are flawed. The high temperature melting method is costly and consumes a lot of energy. The biological method has a long reaction cycle and is likely to cause secondary pollution by foreign biological agents. The effect of the curing method is unstable, and the curing agent is likely to cause secondary pollution to the soil. Patent No. 201510056406.6 introduces a solidification method for soil containing heavy metals, but th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09C1/08B09C1/10C09K17/40
CPCB09C1/08B09C1/105B09C2101/00C09K17/40
Inventor 张大磊赵昱皓路亮
Owner 山东环保产业集团有限公司
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