An organic solution flow battery
A liquid flow battery, an organic technology, applied in the field of organic system flow batteries, can solve the problems of discontinuous renewable energy, high wind and light curtailment rate, and regional environmental restrictions, and achieve excellent cycle stability and good environmental adaptability , the effect of high energy density
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Embodiment 1
[0029] The positive electrolyte is 0.5mol L -1 MEPB and 0.5mol L -1 LiTFSI mixed solution;
[0030] The negative electrolyte is 0.5mol L -1 PMDA solution;
[0031] The non-aqueous solvent is a mixed solvent with a volume ratio of DME / DOL of 1:1.
[0032]
[0033] 3. Cyclic voltammetry test of positive electrode pair
[0034] The electrochemical workstation of American Gamary Company was used to test the electrochemical performance of the positive and negative electrode organic pair with a three-electrode system. The working electrode is a glassy carbon electrode (Tianjin Aida Hengsheng Company), the reference electrode and the counter electrode are lithium metal foils, the carbon powder dispersion is an isopropanol solution of activated carbon, and 0.05wt% Nafion is the binder. The scanning range of the positive and negative electrode pairs is 2.0V~4.0V, the scanning speed is 10, 25, 50, 75, 100mV / s, CV see figure 2 , The redox peak current is linearly fitted to one-half of the swee...
Embodiment 2
[0037] The positive electrolyte is 1.0mol L -1 MEP and 1.0mol L -1 LiTFSI mixed solution;
[0038] The anode electrolyte is 1.0mol L -1 PMDA solution;
[0039] The non-aqueous solvent is a mixed solvent with a volume ratio of DME / DOL of 1:1.
Embodiment 3
[0041] The positive electrolyte is 1.5mol L -1 MEP and 1.5mol L -1 LiTFSI mixed solution;
[0042] The negative electrolyte is 1.5mol L -1 PMDA solution;
[0043] The non-aqueous solvent is a mixed solvent with a volume ratio of DME / DOL of 1:1.
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