Anti-corrosion bonding alloy wire and preparation method thereof

An alloy wire and corrosion-resistant technology, which is applied in the field of high-performance bonding alloy wire and its preparation, can solve the problems of reducing the welding strength of the first solder joint, increasing the cost, and increasing the cost of LED devices, so as to eliminate adverse effects and corrosion Effect of slow reaction, good anti-tarnish properties

Active Publication Date: 2017-05-31
HENAN POLYTECHNIC UNIV +4
View PDF4 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The surface treatment method is to coat a layer of stable metal protective film on the surface of the bonding alloy wire. This protective film can effectively improve the corrosion resistance of the bonding alloy wire and increase the anti-tarnish property. The alloy wire and the alloy wire are dissimilar metals, which will cause the phenomenon of partial balls and golf balls in the bonding alloy wire during the burning process, thereby reducing the welding strength of the first solder joint
The precious metal alloy method is mainly to add high-quality noble metals such as Au, Pd, and Pt to the silver-based alloy to improve the corrosion resistance of the bonding alloy wire. Although the precious metal alloy method can effectively improve the corrosion resistance of the bonding alloy wire, the The cost increase is too high, which in turn increases the cost of the LED device

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Anti-corrosion bonding alloy wire and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] A method for preparing a corrosion-resistant bonding alloy wire, wherein the raw material of the bonding alloy wire is composed of pure Ag with a purity not lower than 99.995%, pure Pd with a purity not lower than 99.99%, pure Pd with a purity not lower than 99.995%. Cu, pure In with a purity of not less than 99.99%, and pure Y with a purity of not less than 99.9%.

[0022] The preparation method of the bonding alloy wire is as follows:

[0023] (1) Preparation of silver-yttrium master alloy. A high-vacuum medium-frequency induction melting furnace is used for the preparation of silver-yttrium master alloy. The upper and lower double crucibles are used for preparation. The material of the crucible is a high-purity graphite crucible, and the two crucibles are placed one above the other. Small holes, and fixed with the lower crucible through surface fit. The preparation process of the silver-yttrium master alloy is as follows: Weigh the yttrium with a mass fraction of 3%...

Embodiment 2

[0028] A method for preparing a corrosion-resistant bonding alloy wire, wherein the raw material of the bonding alloy wire is composed of pure Ag with a purity not lower than 99.995%, pure Pd with a purity not lower than 99.99%, pure Pd with a purity not lower than 99.995%. Cu, pure In with a purity of not less than 99.99%, and pure Y with a purity of not less than 99.9%.

[0029] The preparation method of the bonding alloy wire is as follows:

[0030] (1) Preparation of silver-yttrium master alloy. The preparation of silver-yttrium master alloy adopts a high-vacuum intermediate-frequency induction melting furnace and is prepared by the method of upper and lower double crucibles. The material of the crucible is a high-purity graphite crucible. Small holes, and fixed with the lower crucible through surface fit. The preparation process of the silver-yttrium master alloy is as follows: Weigh the yttrium with a mass fraction of 4% and the silver with a mass fraction of 96%, and p...

Embodiment 3

[0035] A method for preparing a corrosion-resistant bonding alloy wire, wherein the raw material of the bonding alloy wire is composed of pure Ag with a purity not lower than 99.995%, pure Pd with a purity not lower than 99.99%, pure Pd with a purity not lower than 99.995%. Cu, pure In with a purity of not less than 99.99%, and pure Y with a purity of not less than 99.9%.

[0036] The preparation method of the bonding alloy wire is as follows:

[0037] (1) Preparation of silver-yttrium master alloy. A high-vacuum medium-frequency induction melting furnace is used for the preparation of silver-yttrium master alloy. The upper and lower double crucibles are used for preparation. The material of the crucible is a high-purity graphite crucible, and the two crucibles are placed one above the other. Small holes, and fixed with the lower crucible through surface fit. The preparation process of the silver-yttrium master alloy is as follows: Weigh the yttrium with a mass fraction of 5%...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
particle sizeaaaaaaaaaa
Login to View More

Abstract

The invention relates to an anti-corrosion bonding alloy wire and a preparation method thereof. The anti-corrosion bonding alloy wire comprises the following ingredients by mass percent: 3-15 wt% of Pd, 0.5-5.0 wt% of Cu, 0.1-2.0 wt% of In, 0.01-0.1 wt% of Y and the balance of Ag. The preparation method comprises the following steps: preparing Ag-Y intermediate alloy in a high-vacuum intermediate-frequency furnace through a double-layered crucible, wherein local micro-positive-pressure smelting is adopted at the double-layered crucible in the preparation process; performing heat treatment and big-deformation processing in the preparation process of the bonding alloy wire, wherein the heat treatment temperature is 450-550 DEG C, the heat treatment time is 30-120 min, the cooling mode is furnace cooling, and the big-deformation cold-processing compression ratio is 20-25%. The anti-corrosion bonding alloy wire has favorable corrosion resistance and anti-tarnishing property, can meet the requirements for package of various plastic package materials and high-power LEDs, and can be widely applied to package of multi-pin high-density integrated circuits.

Description

technical field [0001] The invention belongs to the technical field of semiconductor materials, and mainly relates to a high-performance bonding alloy wire with good corrosion resistance and discoloration resistance and a preparation method thereof. Background technique [0002] Due to its excellent electrical properties (can reduce high-frequency noise of devices, reduce heat generation of high-power LEDs, etc.) and appropriate cost factors, bonding silver alloy wire can effectively reduce light decay and improve conversion rate in LED packaging The many advantages of alloy wires have led to their application in microelectronic packaging, especially in LED packaging. However, in the existing LED packaging process, the plastic packaging materials contain a small amount of elemental sulfur or sulfur compounds, causing the existing alloy wires to be vulcanized and discolored due to their limited corrosion resistance after plastic packaging. , Blackening and other phenomena, e...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & AuthorityApplications(China)
IPC IPC(8): H01L21/60
CPCH01L24/43H01L24/44H01L2224/44H01L2224/431
Inventor曹军李科
OwnerHENAN POLYTECHNIC UNIV