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A thermal functional composite material and its preparation method and application

A functional composite material and composite material technology, which is applied in the field of solid-liquid phase change composite materials, can solve the problem of inability to meet the use requirements of reversible mutation materials of thermal conductivity, and achieve strong temperature regulation ability, improve thermal conductivity mutation, regulation and control. fast effect

Active Publication Date: 2019-07-16
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

It has been reported in the literature that after compounding phase change materials and non-oriented thermally conductive fillers, the mutation multiple of thermal conductivity has been slightly increased, and about 4 times the mutation will occur, but it still cannot meet the requirements of temperature control, thermal switching, building energy saving, thermal conductivity, etc. Requirements for materials with reversible mutations in thermal conductivity in fields such as stealth, radiation detection, quantum information, thermal storage, and sensing

Method used

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  • A thermal functional composite material and its preparation method and application

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Experimental program
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Embodiment 1

[0036](1) Disperse 100 g of boron nitride with a diameter of 5 microns and a thickness of 100 nanometers into 1 L of water, then add 1 mol / L sodium polystyrene sulfonate and 1 mol / L hydrochloric acid to adjust the pH value to about 4.0 , to ensure complete adsorption of sodium polystyrene sulfonate on boron nitride. Then filter and wash with water and acetic acid three times, and then dry, redisperse the boron nitride adsorbed with sodium polystyrene sulfonate in deionized water, add ferrous chloride and ferric chloride, and add 1,6 - Hexamethylenediamine, until a dark brown suspension is obtained, the amine molecules are washed away with water, and dried at 70° C. to obtain orientable heat-conducting particles under the action of a magnetic field (ie, magnetized boron nitride).

[0037] (2) Heat 100 parts by weight of solid PEG4000 to a liquid state, put it in a water bath to control the temperature and stir above its phase transition temperature, and add 5 parts by weight of...

Embodiment 2

[0039] Others are the same as in Embodiment 1, only the magnetic field intensity is adjusted from 20mT to 60mT.

Embodiment 3

[0041] Others are the same as embodiment 2, only changing boron nitride into graphene.

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Abstract

The present invention provides a heat functional composite material, as well as a preparation method and application thereof. The composite material comprises materials in parts by weight: 100 parts of a phase-change material and 0.01-60 parts of heat conduction filler capable of orientation. For the composite material, at a temperature higher than the phase-transition temperature, applying outer force to achieve orientation of the heat conduction filler in a manner of being vertical to a heat flow direction, and testing to obtain a heat conductivity vertical to the orientation direction; and then changing the direction of the outer force to achieve orientation of the heat conduction filler in a manner of being parallel to the heat flow direction, cooling to be lower than the phase-transition temperature, and testing to obtain a heat conductivity in the orientation direction. The tested heat conductivity can be subjected to reversible mutation up to 5 fold, and the heat functional composite material can be applied to the fields of heat energy storage, heat energy control (such as intelligent switches), building energy saving, heat dissipation of microelectronic devices, sensing, phonon devices, phonon computers and the like.

Description

technical field [0001] The invention relates to the field of thermal functional composite materials, in particular to a solid-liquid phase change composite material with magnetically regulated thermal conductivity reversible mutation. Background technique [0002] Thermal energy is an abundant energy source. 90% of the world's energy production is related to thermal energy flow, but unfortunately only 13% of it can be effectively utilized, and most of the thermal energy is consumed in the form of waste heat diffused to the environment. How to improve the utilization efficiency of thermal energy is the focus that scientists have been paying attention to. Thermal switches are generally made of materials with sudden change in thermal conductivity, that is, the thermal conductivity of the material will change suddenly at a certain temperature, and this change is reversible. At present, the thermal conductivity of pure phase change materials will undergo a sudden change of about...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08K9/04C08K3/38C08L71/02C09K5/06
CPCC08K3/38C08K9/04C08K2003/385C09K5/063C08L71/02
Inventor 郑鲲韦宝杰马永梅曹新宇张京楠尚欣欣
Owner INST OF CHEM CHINESE ACAD OF SCI
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