Low-light-induced-degradation solar cell front side silver paste and preparation method thereof

A technology of solar cells and silver paste, applied in photovoltaic power generation, cable/conductor manufacturing, circuits, etc., can solve the problems of reduced availability, large resistance change of silicon single crystal rods, unfavorable large-scale promotion, etc. Attenuate, reduce the effect of the phenomenon

CN107346671AInactive Publication Date: 2017-11-14SHANGHAI TRANSCOM ELECTRONICS TECH
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Publication Date
2017-11-14
Estimated Expiration
Not applicable · inactive patent

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Abstract

The invention discloses low-light-induced-degradation solar cell front side silver paste and a preparation method thereof. According to the technical scheme, the low-light-degradation solar cell front side silver paste is composed of, by mass percentage, 80-93% of silver powder, 5-15% of organic carrier and 0.5-6% of glass powder, wherein the purity of the silver powder is 99.9-99.999%, the average particle size is 0.5-10 microns, the preferred average particle size is 0.5-3 microns, and the glass powder is TPBC glass powder. The preparation method of the low-light-degradation solar cell front side silver paste includes the following steps: (1) preparing organic carrier; (2) preparing glass powder; (3) mixing silver paste; and (4) dispersing silver paste. The advantage is that the invention relates to a novel tellurate glass powder system, the glass powder is a Te-Pb-Bi-Ga glass system, and the TPBC glass system uses a tellurium-plumbum-bismuth compound combination. A certain amount of Ga element is intentionally added to the glass component in order to reduce the light induced degradation of silicon wafers. Experiments show that the rate of light induced degradation is reduced while the photoelectric conversion efficiency of silicon-based cells is improved.
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Description

technical field

[0001] The present invention relates to a kind of solar cell slurry and preparation method thereof, more specifically, it relates to a kind of low light attenuation solar cell positive silver paste and preparation method thereof. Background technique

[0002] With the shortage of fossil energy and people's concern about carbon dioxide emissions, solar power generation technology has been developed by leaps and bounds. As the main body of solar power generation technology, crystalline silicon solar cell technology has always attracted people's attention, and its photoelectric conversion efficiency has been continuously improved.

[0003] The quality of solar cells depends on the carrier concentration, distribution and mobility in the crystalline silicon material used, and is also affected by the performance of the positive and negative electrodes of the battery. The front electrode directly affects the series resistance, shunt resistance, fill factor and phot...

Examples

Embodiment Construction

[0018] Below in conjunction with the accompanying drawings, the embodiment of the low light attenuation solar cell front silver paste of the present invention and its preparation method will be further described.

[0019] In order to achieve the above object, the present invention adopts the following technical scheme, a front silver paste of a low light attenuation solar cell, composed of the following components by mass percentage: 80% to 93% of silver powder, 5% to 15% of organic carrier, and 0.5% of glass powder ~6%, wherein the silver powder has a purity of 99.9%~99.999%, an average particle size of 0.5um~10um, preferably an average particle size of 0.5um~3um, and the glass powder is TPBG glass powder. The shape of single grain of silver powder is spherical or nearly spherical. The invention relates to a novel tellurate glass powder system, the glass powder is a Te-Pb-B i-Ga glass system, and the TPBG glass system uses a combination of tellurium-lead-bismuth compounds. I...