Surface spouting photocatalytic material enrichment method based on magnetic attraction
A photocatalytic material, magnetic traction technology, applied in chemical instruments and methods, physical/chemical process catalysts, metal/metal oxide/metal hydroxide catalysts, etc. , large loss of nanomaterials, etc., to achieve the effect of low cost, no secondary pollution, and good magnetic separation performance
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[0032] The preparation method of the hydrophilic magnetic composite nano photocatalyst:
[0033] 1) The magnetic iron tetroxide (Fe 3 o 4 ) nanoparticles, nano titanium dioxide (TiO 2 ) The sol is mixed at a mass ratio of 1:3, heated to 80°C, and heated at 300-400r·min -1 Speed stirring 2h, due to electrostatic effect, nano-TiO 2 to Fe 3 o 4 The magnetic nanoparticles have a good coating effect. After the reaction is completed, they are dried continuously at 80°C for 3 days, then ground, and burned in a nitrogen atmosphere at 400°C for 3 hours to obtain magnetic Fe 3 o 4 -TiO 2 Composite nano photocatalyst;
[0034] 2) Hydrophilic group modification: use humic acid (HA) to modify the hydrophilic group, specifically, dissolve 0.1g HA in 200mL NaOH solution with a concentration of 0.01mol / L, and add magnetic Fe 3 o 4 -TiO 2 The composite nano photocatalyst and HA solution were mixed and stirred evenly at a mass volume ratio of 1:200 g / ml at 50°C and 600 rpm / min, and...
Embodiment 1
[0047] A kind of magnetic Fe in the shotcrete coating of river concrete slope 3 o 4 -TiO 2 The surface enrichment method of the composite photocatalytic material specifically comprises the following steps:
[0048] (1) Preparation of hydrophilic magnetic Fe 3 o 4 -TiO 2 Composite photocatalytic materials;
[0049] (2) Preparation of magnetic Fe 3 o 4 -TiO 2 Spraying liquid on the surface of river concrete slope with composite photocatalytic material;
[0050] (3) Surface pretreatment of river concrete slope;
[0051] (4) Slurry spraying on the surface of river concrete slope;
[0052] (5) Magnetic traction enrichment of photocatalytic materials in surface slurries;
[0053] (6) The spray grout is solidified.
[0054] The step (1) prepares hydrophilic magnetic Fe 3 o 4 -TiO 2 The steps of composite photocatalytic material are as follows:
[0055] 1) Preparation of Fe by hydrothermal method 3 o 4 Magnetic nanoparticles: FeCl 3 ·6H 2 O and ethylene glycol were...
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