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A kind of copolyether ester and its preparation method and application

A technology of copolyetherester and methyl ester, applied in the field of copolyetherester and preparation, can solve the problems of complex molding process, unsatisfactory flame retardancy, complicated steps, etc. Effect

Active Publication Date: 2021-02-05
HANGZHOU HONGSHENG TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The steps of the preparation method are relatively complicated, and it is only recorded in this document that the compression spring has the problem of compressing more than 30% without breaking, and there is no relevant record on other properties of the compression spring
Patent CN102432856A introduces a copolyether ester containing hydroxyl-terminated polybutadiene soft segments, which is mixed with additives and then injected into an oval shape, and then molded into a cushion gasket. Although the pressure resistance of the cushion gasket meets the technical requirements, the Does not meet the requirements of flame retardancy, and the molding process is complicated and the cycle is long

Method used

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  • A kind of copolyether ester and its preparation method and application
  • A kind of copolyether ester and its preparation method and application
  • A kind of copolyether ester and its preparation method and application

Examples

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Embodiment 1

[0036] Dimethyl naphthalate (3530g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (650g), low molecular weight nylon 6 dimethyl ester (650g), 1,4-butanediol (3500g), polytetrahydrofuran ether (1600g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D52, and the number average molecular weight Mn is about 31000. The physical and mechanical properties of copolyether esters are shown in Table 1.

Embodiment 2

[0038] Dimethyl naphthalate (3930g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (500g), low molecular weight nylon 6 dimethyl ester (500g), 1,4-butanediol (3700g), polytetrahydrofuran ether (1300g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D56, and the number average molecular weight Mn is about 32000. The physical and mechanical properties of copolyether esters are shown in Table 1.

Embodiment 3

[0040] Dimethyl naphthalate (3130g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (800g), low molecular weight nylon 6 dimethyl ester (800g), 1,4-butanediol (3500g), polytetrahydrofuran ether (1700g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D50, and the number average molecular weight Mn is about 31000. The physical and mechanical properties of copolyether esters are shown in Table 1.

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Abstract

The present invention provides a copolyether ester and its preparation method and application, comprising the steps of: dimethyl naphthalate, p-(methyl ester-phenyl-3-trifluoromethyl-4-amino)-(methyl ester- Phenyl‑3‑trifluoromethyl‑4‑amidoethyl) phenylphosphine oxide, low molecular weight nylon 6 dimethyl ester, 1,4‑butanediol, polytetrahydrofuran ether, catalyst, antioxidant, nucleating agent Add it into the polymerization tank in proportion, and obtain copolyether ester through transesterification reaction and polycondensation reaction; the copolyether ester is injection molded or extruded to obtain a shock-absorbing elastic element mold base, and then undergoes machining and post-processing to obtain a shock-absorbing element , the copolyetherester contains ether ester unit, ether ester amide unit, flame retardant unit, has excellent self-lubrication, wear resistance, creep resistance, bending fatigue ability, flame retardancy, outstanding chemical resistance and comparative With a wide working temperature, the shock absorbing element prepared by the copolyether ester can be widely used in buffer devices in rail transit, vehicles, construction machinery, elevators and other fields.

Description

technical field [0001] The invention relates to the field of cushioning materials, in particular to a copolyether ester, its preparation method and application. Background technique [0002] Thermoplastic copolyetherester elastomer is also often used as an engineering-grade elastomer, which has excellent physical and mechanical properties and is widely used in the automotive industry, electronic appliances, electrical instruments, industrial products, communications, sporting goods, shoemaking, etc. Many fields, especially buffer devices in rail transit vehicles, engineering machinery, elevators and other fields, have a wide range of applications. At present, the industrial polyether ester elastomer mostly uses long-chain polyether ester composed of terephthalic acid (PTA) or dimethyl terephthalate (DMT) and polytetramethyl ether (PTMG) as the soft segment. A short-chain polyester such as butylene terephthalate (PTB) composed of PTA or DMT and 1,4-butanediol is used as a ha...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G69/44
CPCC08G69/44
Inventor 陈建法宋亚昕
Owner HANGZHOU HONGSHENG TECH CO LTD
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