A kind of copolyether ester and its preparation method and application
A technology of copolyetherester and methyl ester, applied in the field of copolyetherester and preparation, can solve the problems of complex molding process, unsatisfactory flame retardancy, complicated steps, etc. Effect
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Embodiment 1
[0036] Dimethyl naphthalate (3530g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (650g), low molecular weight nylon 6 dimethyl ester (650g), 1,4-butanediol (3500g), polytetrahydrofuran ether (1600g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D52, and the number average molecular weight Mn is about 31000. The physical and mechanical properties of copolyether esters are shown in Table 1.
Embodiment 2
[0038] Dimethyl naphthalate (3930g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (500g), low molecular weight nylon 6 dimethyl ester (500g), 1,4-butanediol (3700g), polytetrahydrofuran ether (1300g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D56, and the number average molecular weight Mn is about 32000. The physical and mechanical properties of copolyether esters are shown in Table 1.
Embodiment 3
[0040] Dimethyl naphthalate (3130g), p-(methyl-phenyl-3-trifluoromethyl-4-amino)-(methyl-phenyl-3-trifluoromethyl-4-amidoethyl ) phenylphosphine oxide (800g), low molecular weight nylon 6 dimethyl ester (800g), 1,4-butanediol (3500g), polytetrahydrofuran ether (1700g), tetrabutyl titanate (40g), antioxidant Add SEED (20g) and nucleating agent NAV101 (10g) into the polymerization kettle, and obtain copolyetherester through transesterification reaction and polycondensation reaction. The hardness of the copolyetherester is D50, and the number average molecular weight Mn is about 31000. The physical and mechanical properties of copolyether esters are shown in Table 1.
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