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Method for removing thiol in FCC gasoline through hydrogenation

A technology for gasoline hydrogenation and desulfurization, which is applied in chemical instruments and methods, treatment of hydrocarbon oil, petroleum industry, etc., can solve the problems of difficult control of catalyst product quality, complicated preparation process, and large catalyst composition and content, and achieves catalyst selection. Good properties, high desulfurization activity, and low olefin saturation

Active Publication Date: 2019-02-22
博兴兴业精细化工产业发展有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The composition and content of the above-mentioned catalysts are relatively large, the preparation process is complicated, and it is difficult to control the quality of catalyst products produced in large quantities

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1. Preparation of nickel-doped lanthanum ferrite

[0023] Under stirring conditions, dissolve 2.51mol lanthanum nitrate in 120mL water, add citric acid and stir to dissolve; then add 4.79mol iron nitrate, then add 190g sodium polyacrylate, then add 42g nickel nitrate aqueous solution, continue stirring for 30min, after drying Drying, roasting and grinding to obtain nickel-doped lanthanum ferrite.

[0024] 2. Preparation of silica-alumina carrier

[0025] Dissolve 5g of sodium polyacrylate in nitric acid, then add 38g of microsilica powder and 50g of pseudoboehmite powder, and stir evenly to obtain a mixture of microsilica powder-pseudoboehmite-sodium polyacrylate (abbreviated silicon-aluminum-organic mixture) , take 1 / 8 of the amount for later use, and add citric acid to 4.5g of nickel-doped lanthanum ferrite for later use. Add 300g of pseudo-boehmite powder and 25.0g of fenugreek powder into the kneader, add nitric acid, then add 40.2g of sodium polyacrylate nitric a...

Embodiment 2

[0029] The preparation of nickel-doped lanthanum ferrite is the same as in Example 1, except that 260g of sodium polyacrylate is added, and the preparation of the silica-alumina carrier is the same as in Example 1. The silica-alumina carrier contains 4.4wt% of silicon oxide, 5.7wt% % nickel-doped lanthanum ferrite, 1.6wt% potassium, carrier mesopores accounted for 64.2% of the total pores, and macropores accounted for 25.6% of the total pores. The unit content of sodium polyacrylate in the alumina precursor is 3 times higher than the content of sodium polyacrylate in the silicon source-organic polymer mixture. The preparation method of catalyst 2 is the same as embodiment 1.

Embodiment 3

[0031] The preparation of nickel-doped lanthanum ferrite is the same as in Example 1, except that 220g of polyacrylic acid is added, and the preparation of the silica-alumina carrier is the same as in Example 1. The silica-alumina carrier contains 8.4wt% of silicon oxide, 2.6wt% Nickel-doped lanthanum ferrite, 0.8wt% potassium, the carrier mesopores account for 54.6% of the total pores, and the macropores account for 33.5% of the total pores. The unit content of polyacrylic acid in the alumina precursor is 3.3 times higher than that in the silicon source-organic polymer mixture. The preparation method of catalyst 3 is the same as that of Example 1.

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PUM

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Abstract

The invention relates to a method for removing thiol in FCC gasoline through hydrogenation. A fixed bed reactor is adopted; a catalyst contains a silica-alumina supporter and metal active components including nickel, molybdenum, zinc and strontium supported on the supporter and particularly contains the following components in percentage by weight: 2wt%-15wt% of nickel oxide, 2wt%-18wt% of molybdenum oxide, 0.1wt%-5wt% of zinc oxide, 0.1wt%-2.0wt% of strontium oxide and 65wt%-85wt% of the silica-alumina supporter; and the reaction process conditions are as follows: the reaction temperature is110-240 DEG C, the reaction pressure is 1.1MPa-5.5MPa, the volume velocity is 1.2h<-1>-5.5h<-1>, and the hydrogen-oil volume rate is (7-25) to 1. The catalyst has high thiol removal activity and diolefin hydrogenation selectivity and strong adaptability to different raw materials.

Description

technical field [0001] The invention relates to a method for hydrodemercaptanization of FCC gasoline. Background technique [0002] With the increasingly stringent environmental protection regulations, countries around the world have put forward more and more stringent requirements on the quality of petroleum processed products, especially the stricter restrictions on the sulfur content of petroleum processed products. The sulfides contained in light petroleum products are mainly mercaptans (RSH), sulfides (RSR), etc. Among them, mercaptans have the greatest impact on product quality, not only have a foul smell, strong corrosiveness, but also affect Product stability. [0003] US6692635B2 discloses a method for producing gasoline with low sulfur content, in which a new sweetening technology is adopted. This technology feeds the whole distillate gasoline raw material into a selective hydrogenation reactor to make mercaptans react with olefins or diolefins in gasoline to gen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G45/08B01J23/887
CPCB01J23/8873C10G45/08C10G2300/1037C10G2300/104C10G2300/1044C10G2300/202C10G2300/70
Inventor 黄志祥黄凤玉张丽娥张素珍
Owner 博兴兴业精细化工产业发展有限公司
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