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Method and system for hydrogenation of wax oil

A wax oil hydrogenation and wax oil technology, which is applied in the directions of hydrotreating process, hydrocarbon oil treatment, petroleum industry, etc., can solve the problem that the quality of catalytic cracked gasoline is not the best, there is no combined processing technology, and it is disadvantageous for catalytic cracking light cycle oil. To effectively control the production of high-quality gasoline and other issues, to achieve the effect of increasing the content of aromatics and increasing the octane number

Active Publication Date: 2021-10-08
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] CN103773495A, CN101875856A, CN102465035A and CN1896192A disclose the process technology of blending catalytic cracking light cycle oil in the wax oil hydrotreating process, the main purpose is to produce high-quality catalytic cracking raw materials, or to make the catalytic cracking light cycle oil in the wax oil hydrotreating unit Coupling technology with circulation between catalytic cracking units realizes clean production of catalytic cracking units. However, since wax oil is directly hydrogenated after being mixed with catalytic cracking light cycle oil, the hydrogenation depth of catalytic cracking light cycle oil cannot be effectively controlled. The sulfur content or nitrogen content of the mixed hydrogenation product (catalytic cracking raw material) is used as the control target, which is not conducive to the effective control of the production of high-quality gasoline with catalytic cracking light cycle oil
[0004] In summary, compared with the existing FCC light cycle oil hydrogenation technology and wax oil hydrotreating technology, FCC light cycle oil is usually directly blended into the wax oil hydrotreating unit for hydrogenation, mixing Hydrogenated wax oil obtained after hydrogenation and hydrocracked light cycle oil are used as raw materials for the catalytic cracking unit, that is, the catalytic cracked light cycle oil is hydrogenated and then returned to the catalytic cracking unit. Hydrogen depth, the quality of catalytic cracking gasoline has not reached the best, and, at present, there is no combined processing technology coupled with reaction materials

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  • Method and system for hydrogenation of wax oil

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Embodiment approach

[0054] According to a preferred embodiment of the present invention, the method further includes cutting the catalytically cracked light cycle oil to obtain light fractions and heavy fractions, the cutting temperature is 245-300°C, more preferably 260-280°C;

[0055] Step (3) includes: under the first hydrotreating condition, contacting the first hydrotreating gas phase stream, the heavy fraction, the hydrogen-containing gas and the first hydrotreating catalyst to carry out the first hydrotreating reaction to obtain the first hydrotreating Hydrofinishing stream: under the second hydrofinishing condition, the first hydrofinishing stream, light fraction, hydrogen-containing gas and the second hydrofinishing catalyst are contacted to carry out the second hydrofinishing reaction.

[0056] Even more preferably, the temperature of the second hydrofinishing reaction is lower than the temperature of the first hydrofinishing reaction, preferably the temperature of the second hydrofinish...

Embodiment 1-3

[0129] (1) According to figure 1 In the system shown, the wax oil raw material oil and hydrogen-containing gas enter the hydrotreating reactor, and the hydrotreating reactor is equipped with the first hydrotreating unit 1 (the first hydrotreating catalyst bed), the second hydrotreating Unit 3 (the second hydrotreating catalyst bed layer), and a gas-liquid separator 2 is arranged between them. A part of the first hydrotreated stream (the first hydrotreated stream a) passing through the first hydrotreated catalyst bed is subjected to gas-liquid separation in the gas-liquid separator 2 to obtain the first hydrotreated gas phase stream and the first hydrotreated stream. Hydrogen treatment liquid phase stream, the first hydrotreatment conditions are listed in Table 2;

[0130] (2) Send the remaining part of the first hydrotreated stream (first hydrotreated stream b), the first hydrotreated liquid phase stream and the hydrogen-containing gas into the second hydrotreated catalyst be...

Embodiment 4

[0145] According to the method of Example 2, the difference is that the hydrotreating product stream and the hydrorefining product stream are mixed, and then they are separated and fractionated together. specifically:

[0146] (1) Carry out according to step (1) of embodiment 2;

[0147] (2) According to step (2) of Example 2, the hydroprocessing product stream is obtained;

[0148] (3) According to the step (3) of Example 2, the hydrofining product stream is obtained;

[0149] (4) According to figure 2 In the system shown, the hydrotreated product stream obtained in step (2) is mixed with the hydrorefined product stream obtained in step (3) to obtain a mixed flow, and the mixed flow is entered into a mixing high-pressure separator 101 for high-pressure separation to obtain Mix the hydrogen-rich gas and the mixed high-pressure separated liquid phase stream, and send the mixed high-pressure separated liquid phase stream into the mixed low-pressure separator 102 for low-pres...

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Abstract

The present invention relates to the field of petroleum refining, and discloses a method and system for hydrogenation of wax oil. The method includes: (1) contacting wax oil raw material oil and hydrogen-containing gas with a first hydrogenation treatment catalyst to obtain the first The hydrotreated stream is divided into two parts, the first hydrotreated stream a and the first hydrotreated stream b, and the first hydrotreated stream a is subjected to gas-liquid separation to obtain the first hydrotreated gas phase stream and the first hydrotreated stream Hydrotreating the liquid-phase stream; (2) contacting the first hydrotreating stream b, the first hydrotreating liquid-phase stream, and the hydrogen-containing gas with the second hydrotreating catalyst to obtain a hydrotreating product stream; (3) The first hydrotreating gas phase stream, the catalytic cracking light cycle oil and the hydrofinishing catalyst are contacted to carry out the hydrofinishing reaction to obtain the hydrofinishing product stream. The method and system provided by the invention can produce high-quality catalytic cracking raw materials with flexible process and low energy consumption.

Description

technical field [0001] The invention relates to the field of petroleum refining, in particular to a wax oil hydrogenation method and system. Background technique [0002] Fluid Catalytic Cracking (FCC) is one of the important means of lightening heavy oil, but with the deterioration and heavyness of catalytic cracking raw materials, its operating conditions are becoming more and more stringent, and the yield of light products and products However, the hydroprocessing technology of catalytic cracking raw materials can not only remove the content of impurities such as sulfur, nitrogen, and metals, but also improve the cracking performance of the feed, reduce the severity of FCC operation, improve product distribution, and increase the selectivity of target products. Reduce the yield of dry gas and coke, improve the economics of FCC unit, reduce the sulfur content of the target product, reduce the content of SOx and NOx in the regeneration flue gas, etc. FCC light cycle oil (L...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G67/00
CPCC10G67/00C10G2300/305C10G2400/02C10G65/04C10G65/16
Inventor 刘涛张学辉方向晨李宝忠彭绍忠王仲义
Owner CHINA PETROLEUM & CHEM CORP