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Tripodalcapping ligand and synthetic method thereof, and molybdenum containing complex with tripodalcapping ligand and synthetic method of molybdenum containing complex

一种三足戴帽、配合物的技术，应用在没有C-金属键的6/16组有机化合物、周期表第5/15族元素的化合物、含周期表第6/16族元素的化合物等方向，能够解决多金属簇合物分子不多等问题

Active Publication Date: 2019-10-08
XINYANG UNIV
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  • Claims
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Problems solved by technology

However, there are still not many multimetal cluster molecules with such properties reported so far.

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  • Tripodalcapping ligand and synthetic method thereof, and molybdenum containing complex with tripodalcapping ligand and synthetic method of molybdenum containing complex
  • Tripodalcapping ligand and synthetic method thereof, and molybdenum containing complex with tripodalcapping ligand and synthetic method of molybdenum containing complex
  • Tripodalcapping ligand and synthetic method thereof, and molybdenum containing complex with tripodalcapping ligand and synthetic method of molybdenum containing complex

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[0023] In order to make the purpose, technical solution and advantages of the present application clearer, the technical solution of the present application will be clearly and completely described below in conjunction with specific embodiments of the present application. Apparently, the described embodiments are only some of the embodiments of the present application, rather than all the embodiments. Based on the embodiments in this application, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of this application.

[0024] The molybdenum-containing complex with a three-legged capping ligand of the present invention, or called a molybdenum-containing three-legged capping ligand building block, is tricyan[LMo / W(CN) containing a three-legged capping ligand L 3 ]-type building blocks, the ligands on this building block are easy to be exchanged and modified, so that the ligands or their substit...

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Abstract

The invention provides a novel tripodalcapping ligand and a synthetic method thereof, and molybdenum containing complex with the tripodalcapping ligand and a synthetic method of the molybdenum containing complex. A tripodalcapping ligand L is a heterocyclic compound containing N, and due to the fact that a ligand on the heterocyclic compound is easy to exchange and modify, the ligand or the substituent group of a cluster compound can be modified with purpose when the properties of the obtained cluster compound is not ideal; and meanwhile, a three-cyanogen construction module is used, and thusmultinuclear cluster compound with various types of structures can be conveniently and controllably compounded. According to the novel tripodalcapping ligand and the synthetic method thereof, and themolybdenum containing complex with the tripodalcapping ligand and the synthetic method of the molybdenum containing complex, the yield coefficient is high.

Description

technical field [0001] The application belongs to the field of chemical industry, and specifically relates to a three-legged capping ligand and a synthesis method thereof, a molybdenum-containing complex with a three-legged capping ligand and a synthesis method thereof. Background technique [0002] In recent years, a class of magnetic complexes whose magnetic properties change due to intramolecular electron transfer has attracted interest. The reason for the change of the magnetic properties of this type of complex is: under external stimuli such as temperature changes, light changes, pressure changes, etc., the valence state of the metal ion in the molecule changes; Electron transfer between ions or between metal ions and organic ligands. According to the limited relevant papers published so far, such molecules mainly include mixed-valent bis(multi)metal coordination polymers or clusters containing cyanide bridges and quinone-metal complexes. So far, work on thermally an...

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07F11/00C07F5/02C07F9/6506
CPCC07F5/022C07F9/6506C07F11/005
Inventor 吴艳玲左德松张秋平刘仁植马艳梅
Owner XINYANG UNIV
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