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Ultrahigh-voltage flame-retardant electrolyte and preparation method thereof
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An electrolyte and ultra-high voltage technology, applied in the direction of electrolytic capacitors, circuits, capacitors, etc., can solve problems such as fire and combustion, safety hazards, and large amounts of hot gas, and achieve lower vapor pressure, less hydrogen, and strong flame retardancy. Effect
Inactive Publication Date: 2019-10-22
WUXI TAIWEI ELECTRONICS CO LTD
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Problems solved by technology
[0002] The existing ordinary working electrolyte will generate a large amount of hot gas when the capacitor explodes abnormally, and even cause fire and combustion, which poses a great safety hazard
Method used
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Embodiment 1
[0021] A kind of super high pressure flame retardant electrolyte of the present invention, by weight, it comprises,
[0031] A method for preparing an ultrahigh-voltage flame-retardant electrolyte, which comprises the following steps,
[0032] (1) First mix ethylene glycol, diethylene glycol, ammonium pentaborate, ammonium isosebacate, and PVA-1179, heat to 65°C, keep warm for 25 minutes and keep stirring;
[0033] (2) Then add ammonium dodecanoate and heat to 145°C, keep warm for 10 minutes, cool to 70°C and keep for 210 minutes;
[0034] (3) Finally, add nano-sca...
Embodiment 2
[0036] A kind of super high pressure flame retardant electrolyte of the present invention, by weight, it comprises,
[0046] A method for preparing an ultrahigh-voltage flame-retardant electrolyte, which comprises the following steps,
[0047] (1) First mix ethylene glycol, diethylene glycol, ammonium pentaborate, ammonium isosebacate, and PVA-1179, heat to 72°C, keep warm for 25 minutes and keep stirring;
[0048] (2) Then add ammonium dodecanoate and heat to 145°C, keep warm for 10 minutes, cool to 70°C and keep for 210 minutes;
[0049] (3) Finally, add nano-scal...
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Abstract
The invention relates to an ultrahigh-voltageflame-retardant electrolyte which comprises the following components in parts by weight: 65-75 parts of ethylene glycol, 5-10 parts of diethylene glycol,1-3 parts of nanoscale silicon dioxide, 2-3 parts of ammoniumdodecanedioate, 3-5 parts of ammonium isosebacate, 3-8 parts of ammonium pentaborate, 3-5 parts of PVA-1179, 1-2 parts of o-nitroanisole and and 0.15-0.20 part of tributyl hypophosphite. The preparation method comprises the following steps: (1) firstly, mixing the ethylene glycol, the diethylene glycol, the ammonium pentaborate, the ammonium isodecanedioate and the PVA-1179, heating to 60-75 DEG C, keeping the temperature for 25 minutes and continuously stirring; (2) adding the ammonium dodecanedioate, heating to 145 DEG C, keepingthe temperature for 10 minutes, cooling to 70 DEG C, and keeping the temperature for 210 minutes; and (3) finally adding nanoscale silicon dioxide, uniformly stirring until the solution is transparent, preserving heat for 60 minutes, naturally cooling to 75 DEG C, adding o-nitroanisole and tributyl hypophosphite, and naturally cooling to normal temperature to obtain the electrolyte. The electrolyte is resistant to high temperature and high pressure, the amount of hydrogen generated in the working process of the electrolytic capacitor can be reduced, the electrolyte vapor pressure is reduced, and the flame-retardant effect is good.
Description
technical field [0001] The invention relates to an electrolyte and a preparation method thereof, in particular to a high-voltageflame-retardant electrolyte and a preparation method thereof. Background technique [0002] The existing ordinary working electrolyte will generate a large amount of hot gas when the capacitor explodes abnormally, and even cause fire and combustion, which poses a great safety hazard. Contents of the invention [0003] Purpose of the invention: the purpose of the present invention is to overcome the deficiencies in the prior art, to provide a kind of ultra-high pressure flame-retardant electrolyte and a its preparation method. [0004] Technical solution: In order to solve the above technical problems, the ultra-high voltage flame-retardant electrolyte of the present invention, in parts by weight, includes, [0005] (1) 65-75 parts of ethylene glycol; [0006] (2) Diethylene glycol 5-10 parts; [0007] (3) 1-3 parts of nano-scale silicon dioxi...
Claims
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