The invention discloses a power system of a fuel cell car with an ultra-low-temperature cold starting function. The power system comprises a proton exchange membrane fuel cell and a lithium cell, thefeeding end of the proton exchange membrane fuel cell is connected with a power generation hydrogen input pipe and a power generation air input pipe, the power generation hydrogen input pipe is communicated with a hydrogen cylinder, the power generation air input pipe is communicated with an air compressor, a coolant circulation pipe is arranged between the feeding end and the discharging end ofthe proton exchange membrane fuel cell, an air and exhaust gas pipe, a hydrogen circulation pipe, a condensate water outer discharging pipe and a heating exhaust gas pipe are connected at the discharging end of the proton exchange membrane fuel cell, a plurality of heating units are arranged in the proton exchange membrane fuel cell, each heating unit is arranged between one pair of adjacent mono-cells, an exhaust gas heat insulation pipe is arranged outside the lithium cell, and the heating exhaust gas pipe is communicated with the input end of the exhaust gas heat insulation pipe. The powersystem has the advantages that the system can be started at the ultra-low temperature, hydrogen consuming amount of the system is low when cold starting of the system is implemented, the cold starting time is short, and the system is good in running stability.