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Hindered phenol antioxidant and synthesis method thereof

A technology for antioxidants and hindered phenols, which is applied in the field of hindered phenolic antioxidants and their synthesis, can solve the problems of single antioxidant properties and poor use effect, and can shorten the synthesis time, improve the use effect, and strengthen the tensile property. and the effect of bending resistance

Inactive Publication Date: 2020-03-31
梁山新翔新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the deficiencies of the prior art, the present invention provides a hindered phenolic antioxidant and its synthesis method, which solves the problem that many traditional antioxidant synthesis methods are relatively simple, the synthesized antioxidant has single performance, and the effect of long-term use is poor. question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] An embodiment of the present invention provides a hindered phenolic antioxidant, which consists of the following parts by weight: 10 parts of 2,6-di-tert-butyl-p-nitrophenol, 0.3 parts of potassium hydroxide, 0.1 parts of ferric chloride 50 parts of absolute ethanol, 3 parts of organic zinc, 1 part of phosphite compound, 4 parts of light stabilizer.

[0026] Wherein organic zinc is selected from zinc gluconate or zinc methionine; Phosphite compounds are pentaerythritol distearyl diphosphite, two (2,4-di-tert-butylphenyl) pentaerythritol phosphite, three-(2 , one or more of 4-di-tert-butylphenol) phosphite; light stabilizers are triazines, substituted acrylonitriles, oxalamides, salicylates, benzophenones, benzene One or more of triazoles.

[0027] A kind of synthetic method of hindered phenolic antioxidant, comprises the following steps:

[0028] S1. Prepare 2,6-di-tert-butyl-p-nitrophenol, potassium hydroxide, ferric chloride, absolute ethanol, organic zinc, phosphit...

Embodiment 2

[0033] An embodiment of the present invention provides a hindered phenolic antioxidant, which consists of the following parts by weight: 20 parts of 2,6-di-tert-butyl-p-nitrophenol, 0.6 parts of potassium hydroxide, 0.2 parts of ferric chloride 75 parts of absolute ethanol, 3.5 parts of organic zinc, 1.5 parts of phosphite compounds, and 5 parts of light stabilizer.

[0034] Wherein organic zinc is selected from zinc gluconate or zinc methionine; Phosphite compounds are pentaerythritol distearyl diphosphite, two (2,4-di-tert-butylphenyl) pentaerythritol phosphite, three-(2 , one or more of 4-di-tert-butylphenol) phosphite; light stabilizers are triazines, substituted acrylonitriles, oxalamides, salicylates, benzophenones, benzene One or more of triazoles.

[0035] A kind of synthetic method of hindered phenolic antioxidant, comprises the following steps:

[0036] S1. Prepare 2,6-di-tert-butyl-p-nitrophenol, potassium hydroxide, ferric chloride, absolute ethanol, organic zinc...

Embodiment 3

[0041] An embodiment of the present invention provides a hindered phenolic antioxidant, which consists of the following parts by weight: 30 parts of 2,6-di-tert-butyl-p-nitrophenol, 0.9 parts of potassium hydroxide, 0.3 parts of ferric chloride 100 parts of absolute ethanol, 4 parts of organic zinc, 2 parts of phosphite compounds, and 6 parts of light stabilizer.

[0042] Wherein organic zinc is selected from zinc gluconate or zinc methionine; Phosphite compounds are pentaerythritol distearyl diphosphite, two (2,4-di-tert-butylphenyl) pentaerythritol phosphite, three-(2 , one or more of 4-di-tert-butylphenol) phosphite; light stabilizers are triazines, substituted acrylonitriles, oxamides, salicylates, benzophenones, benzene One or more of triazoles.

[0043] A kind of synthetic method of hindered phenolic antioxidant, comprises the following steps:

[0044] S1. Prepare 2,6-di-tert-butyl-p-nitrophenol, potassium hydroxide, ferric chloride, absolute ethanol, organic zinc, pho...

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PUM

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Abstract

The invention provides a hindered phenol antioxidant and a synthesis method thereof, and relates to the technical field of antioxidants. The hindered phenol antioxidant is prepared from the followingingredients in parts by weight: 10-30 parts of 2, 6-di-tert-butyl-4-nitrophenol, 0.3-0.9 parts of potassium hydroxide, 0.1-0.3 parts of ferric chloride, 50-100 parts of absolute ethyl alcohol, 3-4 parts of organic zinc, 1-2 parts of phosphite ester compounds and 4-6 parts of a light stabilizer. An antioxidant is synthesized from the raw materials such as 2, 6-di-tert-butyl-4-nitrophenol, potassiumhydroxide, ferric chloride, absolute ethyl alcohol, organic zinc, phosphite ester compounds and the light stabilizer, so that the hindered phenol antioxidant synthesized by adopting the method is diversified in performance, the use effect is obviously improved, and after the hindered phenol antioxidant is matched with a high polymer material for use, the tensile property and the bending resistance of the high polymer material can be enhanced.

Description

technical field [0001] The invention relates to the technical field of antioxidants, in particular to a hindered phenolic antioxidant and a synthesis method thereof. Background technique [0002] In recent years, my country's plastics industry has developed rapidly, and the demand for plastic additives is also increasing year by year. As an important polymer material additive, there has been a great increase in both quantity and variety. The synthesis technology of antioxidants is subject to industrial The phenolic antioxidants 264 and phenylethylated phenol developed in the early stage have poor effects on the one hand, and on the other hand, they have been found to have potential toxicity and are gradually only used in the rubber industry with lower requirements. [0003] At present, there are many types of antioxidants synthesized in various ways, which are used in a wide range of fields. However, many traditional antioxidant synthesis methods are relatively simple, and th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K13/02C08K5/00C08K5/32
CPCC08K5/00C08K5/32C08K13/02
Inventor 周捷林农王德龙
Owner 梁山新翔新材料有限公司
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