Polyurethane integral leather cushion water-based coating and polyurethane integral leather cushion
A water-based coating and self-skinning technology, which is applied to the water-based coating of polyurethane self-skinning cushions and the field of polyurethane self-skinning cushions. Effect of strength and flexibility, good color fastness to rubbing
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Embodiment 1
[0057] The preparation of embodiment 1 polyurethane self-skinning cushion
[0058] A polyurethane self-skinning cushion water-based coating, in parts by mass, comprising the following components: 75 parts of water-emulsifiable bisphenol A type epoxy resin, 13 parts of hyperbranched polyethyleneimine, 12.5 parts of water-based polyurethane prepolymer ;
[0059] Among them, the epoxy equivalent of the water-emulsifiable bisphenol A type epoxy resin is 180g·mol -1 ; The molecular weight of hyperbranched polyethyleneimine is 10600; the solid content of waterborne polyurethane prepolymer is 30%, and its end group is isocyanate group;
[0060] The preparation method of described polyurethane self-crusting cushion water-based coating, comprises the following steps:
[0061] S1. After mixing the water-based epoxy resin and hyperbranched polyethyleneimine according to the above mass parts, add water at 80°C and stir for 35 minutes;
[0062] S2. Add water-based polyurethane prepolyme...
Embodiment 2
[0067] The preparation of embodiment 2 polyurethane self-skinning cushion
[0068] A polyurethane self-skinned cushion water-based coating, in parts by mass, comprising the following components: 66 parts of glycerol triglycidyl ether, 17 parts of hyperbranched polyethyleneimine, 20 parts of water-based polyurethane prepolymer;
[0069] Among them, the epoxy equivalent of glycerol triglycidyl ether is 141g·mol -1 ; The molecular weight of hyperbranched polyethyleneimine is 1200; the solid content of water-based polyurethane prepolymer is 15%, and its terminal group is isocyanate group;
[0070] The preparation method of described polyurethane self-crusting cushion water-based coating, comprises the following steps:
[0071] S1. After mixing the water-based epoxy resin and hyperbranched polyethyleneimine according to the above mass parts, add water at 75°C and stir for 360 minutes;
[0072] S2. Add water-based polyurethane prepolymer to the reaction system of step S1 while sti...
Embodiment 3
[0077] The preparation of embodiment 3 polyurethane from crust cushion
[0078] A polyurethane self-skinned cushion water-based coating, in parts by mass, comprising the following components: 84 parts of propylene glycol diglycidyl ether, 9 parts of hyperbranched polyethyleneimine, and 5 parts of water-based polyurethane prepolymer;
[0079] Among them, the epoxy equivalent of propylene glycol diglycidyl ether is 220g·mol -1 ; The molecular weight of hyperbranched polyethyleneimine is 20000; The solid content of waterborne polyurethane prepolymer is 45%, and its end group is isocyanate group;
[0080] The preparation method of described polyurethane self-crusting cushion water-based coating, comprises the following steps:
[0081] S1. After mixing the water-based epoxy resin and hyperbranched polyethyleneimine according to the above mass parts, add water at 85°C and stir for 30 minutes;
[0082] S2. Add the water-based polyurethane prepolymer at 85° C. for 1 hour while stirr...
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