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Resin sheet, laminate body, moulded body, and moulded body production method

A technology for resin sheets and laminates, applied in chemical instruments and methods, synthetic resin layered products, lamination, etc., can solve the problems of insufficient surface hardness and achieve the effect of excellent surface hardness

Inactive Publication Date: 2020-09-15
IDEMITSU UNITECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the film or sheet of Patent Document 2 has been subjected to thermal annealing treatment, the surface hardness is not sufficient

Method used

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  • Resin sheet, laminate body, moulded body, and moulded body production method
  • Resin sheet, laminate body, moulded body, and moulded body production method
  • Resin sheet, laminate body, moulded body, and moulded body production method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0224] use figure 2 The apparatus shown, manufactures resin sheets.

[0225] The operation of this device will be described. The molten resin of polypropylene and petroleum resin having the composition shown in Table 1 extruded from the T-die 52 of the extruder was sandwiched between the metal endless belt 57 and the fourth cooling roll 56 on the first cooling roll 53 between. In this state, the molten resin is quenched while being pressure-contacted by the first and fourth cooling rolls 53 and 56 .

[0226] Next, the resin sheet is sandwiched between the metal endless belt 57 and the fourth cooling roll 56 at an arc portion corresponding to substantially the lower half of the fourth cooling roll 56 , and is brought into planar pressure contact. After the fourth cooling roll 56 is pressed and cooled in a planar manner, the resin sheet that has been in close contact with the metal endless belt 57 is moved onto the second cooling roll 54 as the metal endless belt 57 rotates....

Embodiment 2-6 and comparative example 1-2

[0271] Except having used the molten resin of the composition shown in Table 1 as the molten resin used for manufacture of a resin sheet, it carried out similarly to Example 1, produced the resin sheet, and evaluated it. The results are shown in Table 1.

[0272] [Table 1]

[0273]

[0274] [Manufacture and evaluation of laminated body]

Embodiment 7-10

[0276] The extruder was set to have the molten resin for the production of the resin sheet having the composition shown in Table 2, and the molten resin for the production of the substrate sheet having the composition shown in Table 2, so as to achieve the layer ratio shown in Table 2 (Resin sheet / substrate sheet), except for co-extrusion using the following extruder, the same operation was performed using the same device as in the manufacture of the resin sheet in Example 1, and a resin sheet and a substrate sheet were produced. Laminates composed of sheets were evaluated. The results are shown in Table 2.

[0277] ·The diameter of the extruder for the first layer (resin sheet): 50mm

[0278] ・The diameter of the extruder for the second layer (substrate sheet): 75mm

[0279] It should be noted that, regarding the evaluation method of the isotactic pentad fraction, crystallization rate, pencil hardness, and Martens hardness of the laminates in Table 2, except that the evalua...

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Abstract

This resin sheet comprises polypropylene, and at least one component selected from the group consisting of beta-crystal nucleating agents and petroleum resins. The resin sheet has a crystallisation speed at 130 DEG C of 2.5min<-1> or less, and an isotactic pentad fraction of 95-99mol%.

Description

technical field [0001] The present invention relates to a resin sheet, a laminate, a molded body, and a method for producing the molded body. Background technique [0002] Conventionally, painting and plating have been the main methods for imparting appearance to molded articles. However, since painting emits a large amount of volatile organic compounds (VOC), and plating generates a large amount of waste liquid and harmful substances, either method has a problem of a large environmental load. [0003] In recent years, the method of imparting appearance for the purpose of reducing the environmental burden has been actively studied, and a new method of imparting appearance (decorative molding method) has been developed that applies either printing or surface shape to the sheet. or two, and integrate the sheet with the molded product. [0004] Patent Document 1 discloses a decorative sheet comprising at least one selected from aliphatic petroleum resins, alicyclic petroleum ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12B29C45/14B32B9/00B32B15/08B32B27/32C08K5/00C08K5/16C08L101/00
CPCC08K5/20C08K5/0083C08K5/17C08K5/103B32B7/12B32B2255/10B32B27/16B32B2307/536B32B2307/406B32B2255/28B32B2509/00B32B2255/26B32B2307/714B32B2307/732B32B27/28B32B27/42B32B27/325B32B27/32B32B2270/00B32B2307/412B32B2307/738B32B2307/30B32B2451/00B32B2255/205B32B2307/75B32B2605/003B32B2571/00B32B2250/24B32B27/20B32B27/08B32B2307/306C08L23/10B29C45/14811B29K2623/12B29K2705/00B29K2709/02B32B9/005B32B9/045B32B15/08B32B37/10C08L23/12
Inventor 浅面里美近藤要
Owner IDEMITSU UNITECH CO LTD