A kind of bactericidal composition and its application
A composition, the technology of prothioconazole, applied in the direction of application, fungicide, biocide, etc., can solve the problems of the effective suspension rate of active components, inaccurate measurement, and phytotoxicity, etc., and achieve the physical and chemical properties of the original drug Stable, stable biological activity, and qualified detection indicators
Active Publication Date: 2022-05-06
SHENYANG SINOCHEM AGROCHEMICALS R&D CO LTD +1
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Problems solved by technology
The Chinese authorized patent CN1681390B applied by Bayer and the Chinese authorized patent CN102083802B of ADAMA both report that prothioconazole has two crystal forms, the crystal form 1 is an unstable crystal form with a melting point of 140.3, and the crystal form 2 is a stable crystal form. The melting point of crystal form is 138.3. The unstable crystal form is prone to problems such as condensation and deposition when it is made into preparations, which can lead to inaccurate measurement and phytotoxicity. It is a difficult problem for preparations containing prothioconazole that needs to be solved urgently
[0006] Because the two crystal forms of prothioconazole can be converted to each other under certain conditions in the preparation, it affects the stability of the product. In order to ensure the stability of the product containing prothioconazole within the shelf life, it is urgent to find a method to ensure the stable performance of the preparation product. Composition to address formulation stability issues
Prothioconazole or preparations made of prothioconazole and methoxyacrylates are prone to problems such as a decrease in the effective suspension rate of active components and product creaming due to the interconversion of prothioconazole crystal forms.
Method used
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Embodiment 125
[0021] Embodiment 1 25% prothioconazole suspension concentrate
[0022]
[0023]
Embodiment 2
[0027] Embodiment 2 25% prothioconazole-erythoxystrobin suspension concentrate
[0028] Prothioconazole original drug (97.8%) 12.5% Enoxstrobin technical drug (91.7%) 12.5% Sodium lignosulfonate (Reax907) 5% Magnesium Aluminum Silicate SF104 1% Deionized water Fill to 100%
Embodiment 3
[0032] Example 3 20% prothioconazole-erythoxystrobin emulsifiable concentrate
[0033]
[0034]
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The invention relates to a fungicide composition, mainly a fungicide composition containing a sulfonic acid-based surfactant as a stabilizer and synergist, and the active component is 1-95% by weight, stable and synergist sulfonic acid-based surfactant 1-10%, and other components to 100%; wherein, the active component is prothioconazole or prothioconazole and enoxastrobin, enoxastrobin , pyrastrostrobin, syringstrobin, pyraclostrobin and other methoxyacrylate compositions. The physical and chemical properties of the prothioconazole or prothioconazole and methoxyacrylate fungicidal composition with the sulfonic acid group-containing surfactant as a stabilizing and synergistic agent of the present invention are stable, and the various tests during the product shelf life The index is qualified, and the preparation of the composition can be used to prevent and control plant diseases caused by ascomycetes, basidiomycetes and deuteromycetes, especially has good control effect on wheat scab and is safe to wheat.
Description
technical field [0001] The present invention relates to a fungicide composition, specifically a kind of methoxyacrylates such as prothioconazole or prothioconazole and enoxastrobin, enoxastrobin, pyraclostrobin, syringstrobin, and pyraclostrobin The bactericidal composition and its application include a bactericidal composition and a sulfonic acid-based surfactant as a stabilizing and synergistic agent. Background technique [0002] Prothioconazole is a new broad-spectrum triazolethione fungicide firstly developed by Bayer. Its English name is Prothioconazole, and its structural formula is as follows: [0003] [0004] Chemical name: 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-2,4-dihydro-1,2,4-triazole- 3-thione, molecular formula: C 14 h 15 Cl 2 N 3 OS, molecular weight: 344.2594, density: 1.5g / cm 3 , Boiling point: 486.7°C / 760mmHg, flash point: 248.2°C. [0005] The PCT patent WO2007104658A applied by BASF applied for a Chinese invention paten...
Claims
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IPC IPC(8): A01N43/653A01N37/36A01N37/50A01N43/56A01N43/16A01N47/24A01P3/00
CPCA01N43/653A01N37/36A01N37/50A01N43/56A01N43/16A01N47/24
Inventor 周惠中崔勇董广新丑靖宇李志念
Owner SHENYANG SINOCHEM AGROCHEMICALS R&D CO LTD




