Stabilized blends containing antioxidants
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[0166]The invention will be further illustrated by the following examples, which sets forth particularly advantageous embodiments. While the examples are provided to illustrate the present invention, they are not intended to limit it.
example set 1
[0167]A set of samples is prepared by adding a specific antioxidant known to have compatibility issues to specific mediums. The antioxidant used in this testing is an alkylated phenyl alpha-naphthyl amine (AO-1). The mediums used in this testing include: a polyolefin-based synthetic oil (MEDIUM-1), a mineral oil suitable for various applications including engine oil (MEDIUM-2), and a mineral oil suitable for various applications including greases (MEDIUM-3). The compatibilizers used in this testing include: a nitrogen containing dispersant derived from a 1000 number average molecular weight polyisobutylene succinic anhydride and a polyalkylene polyamine where the dispersant is itself about 15 percent by weight oil (COMPAT-1), a borated nitrogen containing dispersant where the dispersant is derived from a 2000 number average molecular weight polyisobutylene derived succinic anhydride and a mixture of polyalkylene polyamines, where the nitrogen to carbonyl ratio of the dispersant is a...
example set 2
[0171]A second set of samples is prepared by adding a specific antioxidant known to have compatibility issues to specific mediums. The antioxidant used in this testing is a sterically hindered phenolic antioxidant commercially available from BASF (AO-2). The medium used in this testing is a dialkyl diphenyl ether suitable for various applications including specially grease applications (MEDIUM-4). The compatibilizers used in this testing include: COMPAT-3 described above, a quaternary ammonium salt derived from a 1000 number average molecular weight polyisobutylene derived succinic anhydride and a polyalkylene polyamine, quaternized using an alkylene epoxide in combination with an acid (COMPAT-4), a borated nitrogen containing dispersant where the dispersant is derived from a 1000 number average molecular weight polyisobutylene derived succinic anhydride and a mixture of polyalkylene polyamines, where the nitrogen to carbonyl ratio of the dispersant is about 2 and the molar ratio of...
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