Polyvinyl chloride mixture and preparation method therefor

a technology of polyvinyl chloride and mixture, which is applied in the direction of liquid surface applicators, pigment pastes, coatings, etc., can solve the problems of poor impact strength at low temperature, poor heat stability, poor processability, etc., and achieves low elongation, poor toughness, and extended use range of polyvinyl chloride

Active Publication Date: 2016-04-28
SHANDONG RIKE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0020]The present invention fundamentally solves the defects of low elongation at break and poor toughness at low temperature of polyvinyl chloride products, which allow the elongations at break of polyvinyl chloride close to that of polyethylene, which will surely extending the range of use of polyvinyl chloride, and increasing the competitiveness of polyvinyl chlorides in the fields relative to the other plastic products.

Problems solved by technology

Polyvinyl chloride (PVC) resins generally have the following drawbacks: 1. Poor processability; 2. Poor impact strength at low temperature; 3. Poor heat stability; 4. Poor toughness at low temperature.
However, the problem of the toughness of polyvinyl chloride resins at low temperature has not been well solved so far.
And the problem of the toughness of polyvinyl chloride resins has become the major barrier for the development of polyvinyl chloride resins.
Moreover, the major reason that wood materials cannot be replaced by polyvinyl chloride products is that polyvinyl chloride products will be easily cracked while inserting nails, and the fundamental reason for such phenomenon is the low elongation at break and the poor toughness of polyvinyl chlorides.
Besides, cracking of the welding angles of the polyvinyl chloride doors and windows happens easily in winter when temperature is very low, which is also mainly because of the low elongation at break and the poor toughness of polyvinyl chlorides.
However, although anti-impact ACR and MBS can largely increase the notch impact strengths of polyvinyl chlorides, they can hardly effectively improve the toughnesses of polyvinyl chlorides, especially the toughnesses under low temperature, which is not satisfying.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

(1) Preparation of Toughening Modifiers

[0071]0.25 part of water-soluble methyl methacrylate / acrylic acid copolymer was added as a dispersing agent to a 30 L reactor that is equipped with a stirring rake, 0.24 parts of polyoxyethylene lauryl ether was added as an emulsifying agent, then water was added, the total amount of water used and the amount of all the auxiliary raw materials were 250 parts.

[0072]Then 30 parts of high density polyethylene, 0.2 parts of benzoyl peroxide were added. After the temperature of the reaction materials were increased to 80° C. under the stirring rate of 90 rounds / min, 36 parts by weight of chlorine gas was inlet, then the temperature was increased to 135° C. while inletting chlorine gas. The amount of the chlorine gas inlet during the temperature increasing was 20 parts, and the temperature increasing and the chlorine gas inlet were carried out simultaneously. The temperature was kept at 135° C. after reaching 135° C., the rest 16 parts of chlorine ga...

example 2

(1) Preparation of Toughening Modifiers

[0076]Water, 0.1 part of polymethyl methacrylate / acrylic acid copolymer dispersing agent, 0.05 part of benzoyl peroxide were added to a 24 L reactor equipped with a stirring rake, the total amount of water used and the amount of all the auxiliary raw materials were 250 parts. 30 parts of sample 1, 0.2 part of dodecyl sodium sulfate were added then. Under the stirring rate of 60 rounds / min, the temperature of the reaction material was increased to 80° C., then 3 parts of butyl acrylate and 1 part of methyl methacrylate were added, the temperature was kept at 80-85° C., after 3 hours of reaction, the temperature was cooled to below 40° C. The rubber powder with an elongation at break of 1660% was obtained after centrifugation and drying (sample 2).

[0077]The conversion of the reaction was 99.3%, the average particle size D50 of the powder was 310 μm.

(2) Preparation of Polyvinyl Chloride Mixtures and Polyvinyl Chloride Sheet Products

[0078]The prepa...

example 3

(1) Preparation of Toughening Modifiers

[0079]0.25 part of water-soluble methyl methacrylate / acrylic acid copolymer was added as a dispersing agent to a 24 L reactor that is equipped with a stirring rake, 0.24 parts of polyoxyethylene lauryl ether was added as an emulsifying agent, then water was added, the total amount of water used and the amount of all the auxiliary raw materials were 250 parts. Then 30 parts of high density polyethylene, 0.2 parts of benzoyl peroxide were added. After the temperature of the reaction material was increased to 80° C. under stirring (120 rounds / min stirring rate), 36 parts of chlorine gas was inlet, the temperature was increased to 136° C. while inletting chlorine gas, the increase of temperature and the inlet of chlorine gas were carried out simultaneously. After the temperature reached 136° C., the rest 16 parts of chlorine gas was inlet. The rubber powder with an elongation at break of 1720% was obtained after centrifugation and drying (sample 3)...

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Abstract

The present invention discloses a polyvinyl chloride mixture and a preparation method thereof. The mixture comprises the following components in parts be weight: (a) polyvinyl chloride resin of 100 parts and (b) a toughening modifier of 2-20 parts, the toughening modifier being rubber powder whose elongation at break is 1601%-2200% and which contains the percentage of chlorine of 5-45 wt %. The elongation at break of the polyvinyl chloride mixture of the present inventions is greatly improved, and the defect of low elongation at break of the polyvinyl chloride product is substantially solved accordingly; therefore, the application scope of polyvinyl chloride surely will be greatly widened.

Description

FIELD OF THE INVENTION[0001]The present invention relates to a polyvinyl chloride mixture and preparation method thereof, especially to a polyvinyl chloride mixture with good toughness at low temperature and preparation method thereof.BACKGROUND OF THE INVENTION[0002]Polyvinyl chloride (PVC) resins generally have the following drawbacks: 1. Poor processability; 2. Poor impact strength at low temperature; 3. Poor heat stability; 4. Poor toughness at low temperature. At present, a variety of methods have been invented to improve the drawbacks of polyvinyl chloride resins, such as: adding additives to improve the processability of polyvinyl chloride resins; adding anti-impact modifiers to improve the anti-impact property of polyvinyl chloride resins at low temperature; adding heat stabilizers to improve the heat stability of polyvinyl chloride resins. However, the problem of the toughness of polyvinyl chloride resins at low temperature has not been well solved so far. And the problem o...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C08L27/06
CPCC08L27/06C08L2201/08C08L2205/06C08F8/22C08L51/06C08L97/02C08L2205/035C08F255/023C08L23/286C08L33/10C08L51/04C08F220/10C08F110/02
Inventor ZHAO, DONGRI
Owner SHANDONG RIKE CHEM
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