The application relates to a temperature-sensitive adjustable heat rectification porous material and a preparation method thereof, and belongs to the technical field of functional materials and thermal management materials. The temperature-sensitive adjustable heat rectification porous material comprises an asymmetric porous
polymer skeleton and a temperature-sensitive
polymer network embedded in the interior of the
polymer skeleton, wherein the asymmetric porous polymer skeleton has a pore
size difference in the thickness direction, one side of the asymmetric porous polymer skeleton is a small-pore structure, and the other side is a large-pore structure. The temperature-sensitive
polymer network is introduced into the asymmetric porous polymer skeleton, so that the heat rectification is changed from a
static behavior to a dynamic adjustable behavior. Under a low-temperature condition, the temperature-sensitive polymer absorbs water to expand, the pore size of the large-pore side is reduced, the pore
size difference is reduced, and the heat rectification ratio is reduced; under a high-temperature condition, the temperature-sensitive polymer is dehydrated to shrink, the pore size of the large-pore side is increased, the pore
size difference is increased, and the heat rectification ratio is increased. Through the mechanism, the heat rectification ratio can be adjusted and changed in the range of 25-40 DEG C, and the
heat regulation capacity is remarkably improved.