The invention discloses an environmental friendly production method of a MICA active ester. The environmental friendly production method comprises the following steps: oximating, alkylating, chloridizing, cyclizing, and preparing an intermediate. The production method realizes the recycling of the materials, so that the cost is lowered, and the amount of produced wastes and wastewater is reduced; sodium acetate, a byproduct, is recrystallized in the S1 and used for cyclization in the S4, so that the amount of wastewater and the salt content of the waste water are reduced; the conventional process generally uses potassium carbonate to provide an alkaline environment in the S2, the use amount of the potassium carbonate is generally more than 2 equivalent weights, the defects are as follows: 1, the stirring is strenuous if the slat content is too high in the reaction process; 2, a large quantity of water is needed in the later processing to dissolve an inorganic salt, then a large quantity of high salt content wastewater is produced, but the amount of solid salt is greatly reduced in the reaction process after an organic alkali is used, the organic alkali is recycled in the later processing, and the cost and the amount of wastewater are reduced; a batch feeding mode is used in the S3, so that the use amount of sulfonyl chloride is reduced at the same conversion rate; 2-mercaptobenzothiazole, a byproduct produced in the reaction, is recycled in the S5, and is recycled again so as to be used in the synthesis of diphenyl thiazole disulfide.