Polymer pen lithography
A technology of elastomeric polymer and composition, applied in the direction of nanotechnology, nanotechnology, photolithography process of pattern surface, etc., can solve the problems of fragile and expensive two-dimensional cantilever array, etc.
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[0076] Preparation of the polymer pen array master:
[0077] Shipley 1805 (MicroChem, Inc.) photoresist was spin-coated on gold thin film substrates (10 nm Cr adhesion layer containing 100 nm Au thermally evaporated on pre-cleaned oxidized Si wafers). Square well arrays were fabricated by photolithography using a chromium mask. The photoresist pattern was developed in MF319 developer solution (MicroChem, Inc.), and then developed in O 2 Plasma exposure for 30 seconds (200 mTorr) to remove the remaining organic layer. Subsequently, the substrates were respectively placed in gold (Type TFA, Transene) and chromium (Type 1020, Transene) etching solutions. A thorough rinse with MiliQ water is required after each etching step to clean the surface. The photoresist was subsequently rinsed away with acetone to expose the gold pattern. The gold-patterned substrate was placed in KOH etching solution (30% KOH in H 2 O solution:IPA (4:1 v / v)) for about 25 minutes with vigorous stirr...
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