Environment-friendly collagen fiber leather substrate and production method thereof

A technology of collagen fiber and leather base cloth, which is applied in fiber treatment, non-woven fabric, filament/thread forming, etc. It can solve the problems of secondary pollution of leather shavings utilization rate and complex processing process, and achieve fine appearance and moisture permeability good, strong effect

Active Publication Date: 2012-11-21
GUANGZHOU CANUDILO FASHION & ACCESSORIES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In a word, because the chemical method is carried out in the laboratory, and the operation is flexible and convenient, it has achieved good results in the treatment of chromium-containing waste in theory, but in practical application, the products supported by the chemical method are often not very good. The main reason is that the processing process is complicated, there is secondary pollution and the utilization rate of leather shavings is low, so researchers have been doing research on the rational use of chromium-containing shavings for many years, but the leather shavings of tanning enterprises are still It is difficult to be processed in batches, so it is very important to extract collagen fibers of appropriate length from leather waste to produce high value-added products to achieve the purpose of mass utilization of chromium-containing leather waste without causing secondary pollution to the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] The same kind of cowhide shavings are screened from the wet blue leather scraps of the tannery, and processed by a leather processor into ultra-short collagen fibers with an average length of 1mm and a fineness range of 24-32μm, and 95% of the ultra-short Collagen fibers are mixed with PLA bicomponent fibers with a length of 5mm, and the proportion of PLA bicomponent fibers is 5%, while the PLA bicomponent fibers with a length of 5mm are pulped separately, and then a three-layer web forming system is used At the same time, a three-layer net is formed. The top and bottom layers are a mixture of 95% ultra-short collagen fibers and 5% PLA bicomponent fibers. The weights of the top and bottom layers are 70 grams per square meter and 50 grams per square meter respectively, and the middle layer is 100% PLA. Bicomponent fibers with a weight of 10 g / m². The three-layer fiber web is pre-baked and baked. The pre-baked temperature is 90°C, the pre-baked time is 1 minute, the baked...

Embodiment 2

[0028] Small pieces of pigskin of the same type are screened out from the wet blue leather scraps of the tannery, and processed by a leather processing machine into ultra-short collagen fibers with an average length of 2 mm and a fineness range of 30-42 μm, and 90% of the ultra-short collagen fibers The fibers are mixed with PLA bicomponent fibers with a length of 8mm, and the proportion of PLA bicomponent fibers is 10%. At the same time, the PLA bicomponent fibers with a length of 5mm are separately pulped, and then a three-layer web forming system is used at the same time Form a three-layer net, the top and bottom layers are a mixture of 90% ultra-short collagen fibers and 10% PLA bicomponent fibers, the weights of the top and bottom layers are 100 grams per square meter and 80 grams per square meter, and the middle layer is 100% PLA double components Sub-fiber, the weight is 15 grams per square meter. The three-layer fiber web is pre-baked and baked. The pre-baked temperatu...

Embodiment 3

[0033] From the wet blue leather scraps of the tannery, the same kind of pigskin shavings are screened out, and processed by a leather processing machine into ultra-short collagen fibers with an average length of 1mm and a fineness range of 35-45μm, and 94% of the ultra-short Collagen fibers are mixed with PLA bicomponent fibers with a length of 6mm, and the proportion of PLA bicomponent fibers is 6%. At the same time, PLA bicomponent fibers with a length of 6mm are pulped separately, and then a three-layer web forming system is adopted At the same time, a three-layer net is formed. The upper and lower layers are a mixture of 94% ultra-short collagen fibers and 6% PLA bicomponent fibers. The weights of the upper and lower layers are 120 grams per square meter and 80 grams per square meter respectively. Component fibers with a weight of 10 g / m2. The three-layer fiber web is pre-baked and baked. The pre-baked temperature is 100°C, the pre-baked time is 1 minute, the baked temper...

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Abstract

At present, researchers do the research of reasonable utilization of chrome-containing leather shavings all the time; however, the leather shavings of leather making enterprises are difficult to treat in batch. The invention provides an environment-friendly collagen fiber leather substrate which is characterized by comprising an intermediate-layer fiber web, a surface-layer fiber web tightly connected on the upper surface of the intermediate-layer fiber web, and a bottom-layer fiber web tightly connected on the lower surface of the intermediate-layer fiber web, wherein the surface-layer fiberweb and the bottom-layer fiber web respectively comprise the components by mass percentage of: 90 to 97 percent of collagen fibers, 3 to 10 percent of polylactic acid bi-component fibers; the intermediate-layer fiber web is made of polylactic acid bi-component fibers; the weight of the surface-layer fiber web and the weight of the bottom-layer fiber web are both 30 to 150 grams per square meter; and the weight of the intermediate-layer fiber web is 10 to 30 grams per square meter. The non-woven synthetic leather substrate prepared by using collagen fiber extracted from leather leftovers has good simulation performance, avoids secondary pollution to the environment, and is beneficial to the follow-up coating of PU (polyurethane).

Description

technical field [0001] The invention relates to a synthetic leather base cloth used in clothing and home textile industries, in particular to an environment-friendly collagen fiber leather base cloth. Background technique [0002] The traditional tanning industry uses animal skin as the basic raw material, and the finished product only accounts for about 50% of the original skin weight, and the rest is a large amount of solid waste. As a big country in tanning, my country produces about 1.4 million tons of leather corner waste (mainly chrome-containing leather waste) every year, accounting for almost one-half of the world's total. Therefore, the proportion of chromium-containing scraps is relatively high, so there is a phenomenon that while the leather industry is developing rapidly, the amount of leather waste is also increasing, which makes my country's leather industry face the severe challenge of sustainable development and increasingly serious environmental pollution pro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D04H3/02D04H3/14D01D5/34D21F11/00D21F5/00D21G1/00D04H3/015D04H3/153
Inventor 钱程
Owner GUANGZHOU CANUDILO FASHION & ACCESSORIES CO LTD
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