Coloring composition for color filter, color filter, and display element
A coloring composition and color filter technology, which is applied in the field of middle use, can solve problems such as pigment particle size, and achieve the effects of excellent chromaticity characteristics, excellent developability and storage stability
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[0199] Examples are given below to further specifically describe the embodiment of the present invention. However, the present invention is not limited to the following examples.
[0200]
[0201] Hereinafter, the abbreviations of the raw materials used in "(B) Synthesis of a copolymer" are as follows.
[0202] THF: Tetrahydrofuran
[0203] EEMA: 1-Ethoxyethyl methacrylate
[0204] MA: methacrylic acid
[0205] nBMA: n-butyl methacrylate
[0206] MMA: methyl methacrylate
[0207] AIBN: 2,2'-azobisisobutyronitrile
[0208] DAMA: Dimethylaminoethyl methacrylate
[0209] EHMA: 2-Ethylhexyl methacrylate
[0210] BzMA: benzyl methacrylate
[0211] PME-200: Methoxypolyethylene glycol monomethacrylate (manufactured by NOF Corporation)
Synthetic example 1
[0213] 600.30 g of THF, 10.80 g of lithium chloride (THF solution with a concentration of 3.63% by mass), and 3.84 g of diphenylethylene were added to the reaction vessel, and cooled to -60°C. Then, 9.60 g of n-butyllithium (15.36% by mass concentration of hexane solution) was added and aged for 10 minutes.
[0214] Next, a mixed solution of 103.84 g of nBMA and 13.45 g of EEMA was dripped over 30 minutes, and the reaction was continued for 15 minutes after the dripping. Then, it was measured by gas chromatography (hereinafter abbreviated as GC) to confirm the disappearance of the monomer.
[0215] Next, 32.25 g of DMMA was dripped, and reaction was continued for 30 minutes after dripping. Then, after measuring by GC and confirming the disappearance of the monomer, 3.42 g of methanol was added to stop the reaction.
[0216] 220 g of a propylene glycol monomethyl ether acetate solution having a concentration of 50% by mass of the obtained copolymer was heated at 160° C. to re...
Synthetic example 2
[0218] 55.7 g of THF, 4.65 g of lithium chloride (THF solution with a concentration of 4.54% by mass), and 0.45 g of diphenylethylene were added to the reaction vessel, and cooled to -60°C. Then, 1.22 g of n-butyllithium (15.36% by mass concentration of hexane solution) was added, followed by aging for 10 minutes.
[0219] Next, a mixed solution of 1.66 g of EEMA, 9.9 g of nBMA, and 4.14 g of MMA was dropped over 120 minutes, and the reaction was continued for 15 minutes after the dropwise addition. Then GC was performed to confirm the disappearance of the monomer.
[0220] Next, 3.96 g of DMMA was dripped, and reaction was continued for 30 minutes after dripping. Then, after measuring by GC and confirming the disappearance of the monomer, 0.41 g of methanol was added to stop the reaction.
[0221] 16.44 g of water was added to 65.64 g of a 25% by mass concentration of propylene glycol monomethyl ether acetate solution of the obtained precursor polymer, and the mixture was h...
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