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Improvement to the high-pressure loop in a process for synthesis of urea

一种高压回路、尿素的技术,应用在有机化合物的制备、脲衍生物制备、化学仪器和方法等方向,能够解决大型设备限制等问题,达到增大产率、降低耗费、好转换率的效果

Active Publication Date: 2011-11-23
CASALE SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

CO 2 The stripping process has some advantageous features but is limited in large plants especially stripping columns

Method used

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  • Improvement to the high-pressure loop in a process for synthesis of urea
  • Improvement to the high-pressure loop in a process for synthesis of urea
  • Improvement to the high-pressure loop in a process for synthesis of urea

Examples

Experimental program
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Embodiment Construction

[0049] refer to figure 1 , The high-pressure synthesis circuit 1 of the production plant for the production of urea basically includes a reactor 2 containing a reaction zone, a steam-heated hot stripping column 3 and a condenser 4 .

[0050] Carbon dioxide is sent through line 5 and ammonia is sent through line 6 and through injector 7 . Carbon dioxide enters reactor 2 through line 8 and reacts with ammonia to form aqueous urea solution 9 comprising urea, ammonium carbamate and ammonia.

[0051] Said solution 9 is sent to an adiabatic stripper 10 which also receives a carbon dioxide feed 11 . An adiabatic stripper 10 is located between the reactor 2 and the steam-heated stripper 3 , ie upstream of said stripper 3 .

[0052] The output of adiabatic stripper 10 is urea solution 12 and gas phase 13, and urea solution 12 comprises urea, ammonium carbamate, and ammonia content is lower than input solution 9, and gas phase 13 comprises ammonia and CO 2 . The urea solution 12 is ...

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Abstract

A process and a related plant layout for producing urea are disclosed, wherein the high-pressure loop (1) comprises a synthesis reactor (2), a thermal stripper (3), a condenser (4), and an adiabatic CO2 stripper (10) disposed upstream said thermal stripper, separating a vapour phase (13) containing ammonia from the urea solution (9) discharged from the reactor, and recycling said vapour phase to the reactor. The adiabatic stripper (10) can be incorporated in a reactor (200) having a top reaction zone and a bottom adiabatic stripping zone. A revamping method for a conventional urea plant in accordance with the inventive process is also disclosed.

Description

technical field [0001] The invention relates to a new process for producing urea. The invention provides an improvement to the high-pressure synthesis loop of the traditional process and is suitable for new equipment and for improving existing self-stripping urea production equipment and carbon dioxide stripping urea production equipment. Background technique [0002] The self-stripping process or thermal stripping process is a well-known process for the synthesis of urea. It is commonly called the Snamprogetti process and was researched by Snamprogetti in the late 1960s. A disclosure of this process and associated equipment can be found, for example, in GB1542371. Worldwide, many urea production facilities utilize this process. [0003] Basically, the self-stripping process provides ammonia NH 3 with carbon dioxide CO 2 reaction between. The nitrogen to carbon molar ratio N / C in this reactor is usually about 3.2-3.4. [0004] The aqueous urea solution containing free...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C273/04
CPCB01D19/0015B01J2219/00108B01J2219/00006C07C273/04B01J2219/00024
Inventor 费德里柯·扎尔迪安德烈亚·斯科托
Owner CASALE SA